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Nanotechnologies in Russia

, Volume 8, Issue 1–2, pp 81–91 | Cite as

Structure and properties of composites based on polyethylene oxide and molecular silicasol

  • O. A. Serenko
  • V. G. Shevchenko
  • A. S. ZhiltsovEmail author
  • V. E. Chuprakov
  • T. V. Zaderenko
  • O. T. Gritsenko
  • M. V. Mironova
  • O. B. Gorbatsevich
  • V. V. Kazakova
  • V. G. Kulichikhin
  • A. M. Muzafarov
Article

Abstract

In this work the possibility of forming nanocomposite materials based on polyethylene oxide and hybrid organo-inorganic “core-shell” systems known as molecular silicasols with a modified external layer is studied. The chemical structure of a particle shell similar to the polymer matrix monomeric unit allows one to decrease the surface tension on the disperse phase-disperse medium interface. The level of compatibility of the components and its influence on the molecular weight of the polymer matrix was estimated based on interferometry and viscometry data, as well as an analysis of the concentration dependence of MFI, dielectric, and mechanical properties of the composites.

Keywords

Filler Content Melt Flow Index Polyethylene Oxide Crystallinity Degree Dielectric Permittivity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    B. D. Summ and N. I. Ivanova, “Fields and Methods of Colloid Chemistry in Nanochemistry,” Usp. Khim. 69(11), 995–1008 (2000).CrossRefGoogle Scholar
  2. 2.
    G. Allegra, G. Raos, and M. Vacatello, “Theories and Simulations of Polymer-Based Nanocomposites: From Chain Statistics to Reinforcement,” Prog. Polym. Sci. 33, 683–731 (2008).CrossRefGoogle Scholar
  3. 3.
    H. Zou, S. Wu, and J. Shen, “Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications,” Chem. Rev. 108, 3893–3957 (2008).CrossRefGoogle Scholar
  4. 4.
    M. Tanahashi, “Development of Fabrication Method of Filler/Polymer Nanocomposites: with Focus on Simple Melt-Compouning Based Approach without Surface Modification of Nanofillers,” Materials 3, 1593–1619 (2010).CrossRefGoogle Scholar
  5. 5.
    R. Qiao, H. Deng, K. W. Putz, and L. C. Brinson, “Effect of Particle Agglomeration and Interphase on the Glass Transition Temperature of Polymer Nanocomposites,” J. Polymer Sci. Part B: Polymer Phys. 49, 740–748 (2011).CrossRefGoogle Scholar
  6. 6.
    O. Aso, J. I. Eguiazarbal, and J. Nazarbal, “The Influence of Surface Modification on the Structure and Properties of a Nanosilica Filled Thermoplastic Elastomer,” Composites Sci. Techn. 67, 2854–2863 (2007).CrossRefGoogle Scholar
  7. 7.
    A. V. Bystrova, N. V. Voronina, N. V. Gaevoi, E. V. Getmanova, V. M. Meshkov, O. B. Gorbatsevich, A. M. Muzafarov, A. N. Ozerin, E. V. Egorova, and E. A. Tatarinova, “Synthesis and Control of Molecular Parameters of Hyperbranched Silicon-Containing Polymers and Polymeric Nanocomposites on Their Base,” Ross. Nanotekhnol. 3(5–6), 42–46 (2008).Google Scholar
  8. 8.
    A. M. Muzafarov, N. G. Vasilenko, E. A. Tatarinova, G. M. Ignat’eva, V. D. Myakushev, M. A. Obrezkova, O. B. Meshkov, N. V. Voronina, and O. V. Novozhilov, “Macromolecular Nanoobjects Are the Trend of Polymer Chemistry,” Vysokomolek. Soed. 53(7), 1217–1230 (2011).Google Scholar
  9. 9.
    A. M. Muzafarov and N. G. Vasilenko, “Dendrimers Are the New Way to Organize Polymeric Medium,” Priroda, No. 6, 3–10 (2011).Google Scholar
  10. 10.
    D. B. Cordes, P. D. Lickiss, and F. Rataboul, “Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes,” Chem. Rev. 110, 2081–2173 (2010).CrossRefGoogle Scholar
  11. 11.
    N. V. Voronina, I. B. Meshkov, V. D. Myakushev, T. V. Laptinskaya, V. S. Papkov, M. I. Buzin, M. N. Il’ina, A. N. Ozerin, and A. M. Muzafarov, “Hybrid Organo-Inorganic Globular Nanospecies: Transition from Macromolecule to Particle,” J. Polymer Sci. A 48, 4310–4322 (2010).CrossRefGoogle Scholar
  12. 12.
    N. Hao, M. Bohning, and A. Schonhals, “Dielectric Properties of Nanocomposites Based on Polystyrene and Polyhedral Oligomeric Phenethyl-Silsesquioxanes,” Macromolecules 40, 9672–9679 (2007).CrossRefGoogle Scholar
  13. 13.
    Q. Zhang and L. A. Archer, “Poly(ethylene oxide)/Silica Nanocomposites: Structure and Rheology,” Langmuir 18, 10435–10442 (2002).CrossRefGoogle Scholar
  14. 14.
    Q. Zhang and L. A. Archer, “Optical Polarimetry and Mechanical Rheometry of Poly(ethylene Oxide)-Silica Dispersions,” Macromolecules 37, 1928–1936 (2004).CrossRefGoogle Scholar
  15. 15.
    N. I. Korotkikh, N. N. Matveev, and A. S. Sidorkin, “Pyroelectric Properties of Polyethylene Oxide,” Fiz. Tverd. Tela 61(6), 1215–1217 (2009).Google Scholar
  16. 16.
    M. A. S. A. Samir, F. Alloin, W. Gorecki, J.-Y. Sanchez, and A. Dufresne, “Nanocomposite Polymer Electrolytes Based on Poly(oxyethylene) and Cellulose Nanocrystals,” J. Phys. Chem. B 108, 10845–10852 (2004).CrossRefGoogle Scholar
  17. 17.
    I. B. Meshkov, V. V. Kazakova, O. B. Gorbatcevich, N. V. Voronina, V. D. Myakouchev, and A. M. Muzafarov, “MQ-Type Polymers Based on Hyperbranched Polyethoxysiloxane and Molecular Silicasoles,” Polymer Prep. 47(2), 1152 (2006).Google Scholar
  18. 18.
    V. V. Kazakova, A. S. Zhiltsov, O. B. Gorbatsevitch, I.B. Meshkov, M. V. Pletneva, N. V. Demchenko, G. V. Cherkaev, and A. M. Muzafarov, “Synthesis and Characterization of Hybrid Core-Shell Systems Based on Molecular Silicasols,” J. Inorg. Organometal. Polym. Mater. 22(3), 564–576 (2012).CrossRefGoogle Scholar
  19. 19.
    Z. Grubisic, R. Rempp, and H. Benoit, “A Universal Calibration for Gel Permeation Chromatography,” J. Polym. Sci. B 34, 1707–1713 (1996).CrossRefGoogle Scholar
  20. 20.
    A. E. Chalykh, “Diffusion Is a Way to Research Polymer Systems,” Vysokomolek. Soed. 43(12), 2304–2328 (2001).Google Scholar
  21. 21.
    A. E. Chalykh and V. K. Gerasimov, “Phase Equilibrium and Phase Structure of Polymers Mixtures,” Usp. Khim. 73(1), 63–78 (2004).CrossRefGoogle Scholar
  22. 22.
    Privalko, V.P., Handbook on Physical Chemistry of Polymers: Properties of Solid Polymers (Naukova Dumka, Kiev, 1984) [in Russian].Google Scholar
  23. 23.
    Yu. S. Lipatov, Physical Chemistry of Multicomponent Polymer Systems, Vol. 2: Polymer Systems and Melts (Naukova dumka, Kiev, 1986), p. 299 [in Russian].Google Scholar
  24. 24.
    D. R. Paul and C. B. Bucknall, Polymer Blends, Vol. 2: Performance (John Wiley & Sons, New York, 2000; Nauchnye osnovy i tekhnologii, St. Petersburg, 2009).Google Scholar
  25. 25.
    B. J. Anderson and C. F. Zukoski, “Rheology and Microstructure of Entangled Polymer Nanocomposite Melts,” Macromolecules 42, 8370–8384 (2009).CrossRefGoogle Scholar
  26. 26.
    Wunderlich, B., Macromolecular Physics, Vol. 3: Crystal Melting (Acad. Press, New York, London, Toronto, Sydney, San Francisco, 1980; Mir, Moscow, 1984).Google Scholar
  27. 27.
    T. Blythe and D. Bloor, Electrical Properties of Polymer (Univ. Press, Cambridge, 2005; Fizmatlit, Moscow, 2008).Google Scholar
  28. 28.
    R. J. Sengwa and S. Choudhary, “Dielectric Properties and Structural Dynamics of Melt Compounded Hot-Pressed Poly(ethylene Oxide)-Organophilic Montmorillonite Clay Nanocomposite Films,” Bull. Mater. Sci. 35(1), 19–25 (2012).CrossRefGoogle Scholar
  29. 29.
    S. Havriliak and S. Negami, “A Complex Plane Representation of Dielectric and Mechanical Relaxation Processes in Some Polymers,” Polymer 8, 161–210 (1967).CrossRefGoogle Scholar
  30. 30.
    F. Kremer and A. Schonhals, Broadband Dielectric Spectroscopy (Springer-Verlag, Berlin, 2003).CrossRefGoogle Scholar
  31. 31.
    K. C. Kao, Dielectric Phenomena in Solids: with Emphasis on Physical Concepts of Electronic Processes (Elsevier, London, 2004).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • O. A. Serenko
    • 1
  • V. G. Shevchenko
    • 1
  • A. S. Zhiltsov
    • 1
    Email author
  • V. E. Chuprakov
    • 2
  • T. V. Zaderenko
    • 1
  • O. T. Gritsenko
    • 1
  • M. V. Mironova
    • 3
  • O. B. Gorbatsevich
    • 1
  • V. V. Kazakova
    • 1
  • V. G. Kulichikhin
    • 3
  • A. M. Muzafarov
    • 1
  1. 1.Institute of Synthetic Polymeric MaterialsRussian Academy of SciencesMoscowRussia
  2. 2.Moscow State Pedagogical UniversityMoscowRussia
  3. 3.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

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