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Russian Journal of Physical Chemistry B

, Volume 13, Issue 1, pp 184–189 | Cite as

Thermoplastic Aluminoborophosphate-Aniline Polycomplexes

  • A. Yu. ShaulovEmail author
  • E. M. Nechvolodova
  • R. A. Sakovich
  • L. V. Vladimirov
  • A. V. Grachev
  • L. A. Tkachenko
Chemical Physics of Polymer Materials
  • 1 Downloads

Abstract

Products are obtained from interaction between oligomeric aluminoborophosphate (ABP) and aniline, both complexes based on hydrogen bonds, as confirmed with IR spectroscopy and quantum chemical calculations. Nitrogen and hydrogen atoms of an amino group in aniline form hydrogen bonds with hydrogen and oxygen atoms of a phosphate group in ABP, respectively, with a total energy of 14.2 kcal/mol. Aniline, when added to ABP surrounded with a shell of water molecules, displaces two water molecules from the surface of the chain. The energy gain is 9.1 kcal/mol. IR spectroscopy data show that there are strong donor-acceptor interactions between water molecules and aluminum and phosphorus atoms of ABP in the solid-state polycomplex sample. The thermoplastic oligomeric complexes leads to an increase in the softening temperature and fluidity with an increase in an amount of aniline. This means that polyoxide inorganic polymer (metal phosphate) is possible to be modified with a monofunctional amine under “mild” conditions. We showed that the water resistance of the polycomplex is greater than that of ABP.

Keywords

polycomplexes inorganic polyoxides aluminoborophosphate aniline water resistance 

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References

  1. 1.
    S. L. Golynko-Vol’fson, M. M. Sychev, L. G. Sudakas, and L. I. Skoblo, Chemical Principles of Technology and Applications of Phosphate Ligaments and Coatings (Khimiya, Leningrad, 1968) [in Russian].Google Scholar
  2. 2.
    V. A. Kopeikin, A. P. Petrova, and I. L. Rashkovan, Materials Based on Metal Phosphates (Khimiya, Moscow, 1976) [in Russian].Google Scholar
  3. 3.
    V. A. Kopeikin, B. C. Klement’eva, and B. L. Krasnyi, Refractory Solutions Based on Phosphate Binders (Metallurgiya, Moscow, 1986) [in Russian].Google Scholar
  4. 4.
    RF Patent No. 2422489, Byull. Izobret., No. 18 (2011).Google Scholar
  5. 5.
    S. V. Afanas’ev, V. N. Makhlai, M. P. Mikhailin, and R. V. Korotkov, RF Patent No. 2277046, Byull. Izobret., No. 15 (2006).Google Scholar
  6. 6.
    V. N. Makhlai, S. V. Afanas’ev, O. S. Roshchenko, and I. V. Kuz’min, RF Patent No. 2354489, Byull. Izobret., No. 13 (2009).Google Scholar
  7. 7.
    M. M. Sychev, Inorganic Adhesives (Khimiya, Leningrad, 1986) [in Russian].Google Scholar
  8. 8.
    S. V. Afanas’ev, and I. V. Kuz’min, Bashk. Khim. Zh. 119 (5), 46 (2012).Google Scholar
  9. 9.
    A. Yu. Shaulov, V. K. Skachkova, O. B. Salamatina, S. N. Rudnev, A. N. Shchegolikhin, S. M. Lomakin, U. Eichhoff, S. Steuernagel, A. A. Samoilenko, and A. A. Berlin, Polymer Sci., Ser. A 48, 228 (2006).CrossRefGoogle Scholar
  10. 10.
    E. M. Nechvolodova, R. A. Sakovich, A. V. Grachev, N. N. Glagolev, M. V. Motyakin, A. Yu. Shaulov, and A. A. Berlin, Russ. J. Phys. Chem. B 36, 499 (2017).CrossRefGoogle Scholar
  11. 11.
    E. M. Nechvolodova, A. V. Grachev, R. A. Sakovich, L. V. Vladimirov, D. P. Shashkin, L. A. Tkachenko, A. Yu. Shaulov, and A. A. Berlin, Russ. J. Phys. Chem. B 36, 839 (2017).CrossRefGoogle Scholar
  12. 12.
    E. K. U. Gross and W. Kohn, Adv. Quantum Chem. 21, 255 (1990).CrossRefGoogle Scholar
  13. 13.
    A. D. Becke, J. Chem. Phys. 98, 1372 (1993).CrossRefGoogle Scholar
  14. 14.
    F. Furche, R. Ahlrichs, C. Hattig, et al., Comput. Mol. Sci. 4, 91 (2014).CrossRefGoogle Scholar
  15. 15.
    F. Weigend and R. Ahlrichs, Phys. Chem. Chem. Phys. 7, 3297 (2005).CrossRefGoogle Scholar
  16. 16.
    L. M. Mentel and E. J. Baerends, J. Chem. Theory Comput. 10, 252 (2014).CrossRefGoogle Scholar
  17. 17.
    M. Jastrzebski, M. Sitarz, M. Rokita, and K. Bulat, Spectrochim. Acta, Part A 49, 722 (2011).CrossRefGoogle Scholar
  18. 18.
    D. Huminick and F. C. Hawthorne, Rev. Mineral. Geochem. 48, 123 (2002).CrossRefGoogle Scholar
  19. 19.
    A. Bellamy, The Infrared Spectroscopy of Complex Molecules (Chapman and Hall, London, 1975; Mir, Moscow, 1963).CrossRefGoogle Scholar
  20. 20.
    W. A. P. Luck, A Comprehensive Treatise (Plenum, New York, 1973), Chap. 4, p. 320.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. Yu. Shaulov
    • 1
    Email author
  • E. M. Nechvolodova
    • 1
  • R. A. Sakovich
    • 1
  • L. V. Vladimirov
    • 1
  • A. V. Grachev
    • 1
  • L. A. Tkachenko
    • 1
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

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