Catalytic Decomposition of Ammonia on Coatings Consisting of Organoboron and Platinum Nanoparticles
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Comparative characteristics of catalytic activity of electroneutral and positively charged coatings consisting of organoboron nanoparticles with a composition (C2B10H4)n or platinum in ammonia decomposition have been obtained for the first time. The charge on the coatings was created by the supply of a positive voltage of +6 or +10 V. It has been found that, for the same mass of the coatings at 700 K and a pressure of 5 × 10–7 Torr, the rate of ammonia decomposition on a coating consisting of organoboron nanoparticles is 28–43% of the rate of NH3 decomposition on the coating consisting of platinum nanoparticles depending on the voltage supplied to the coatings.
Keywordsorganoboron nanoparticles platinum nanoparticles catalysis ammonia decomposition
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- 2.M. V. Grishin, A. K. Gatin, V. G. Slutskii, V. A. Kharitonov, and B. R. Shub, Khim. Fiz. 33 (6), 73 (2014).Google Scholar