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Superoxide radicals in the kinetics of nitroxide-inhibited oxidation of methyl linoleate in micelles

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

The kinetics of the oxidation of methyl linoleate in micelles inhibited by stable nitroxides under the conditions of initiation by superoxide radicals was studied. Multiple breakdown of the oxidation chains was observed in this process. The antioxidant activity of nitroxides increased when the reduction potential of the oxoammonium cation/nitroxide pair decreased and their lipophilicity increased.

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References

  1. E. Damiani, G. Paganga, L. Greci, and C. Rice-Evans, Biochem. Pharmacol. 48, 1155 (1994).

    Article  CAS  Google Scholar 

  2. U. A. Nilsson, G. Carlin, and A. C. Bylund-Fellenius, Chem.-Biol. Interact. 74, 325 (1990).

    Article  CAS  Google Scholar 

  3. J. Antosiewicz, J. Popinigis, M. Wozniak, et al., Free Radic. Biol. Med. 18, 913 (1995).

    Article  CAS  Google Scholar 

  4. T. Offer and A. Samuni, Free Radic. Biol. Med. 32, 872 (2002).

    Article  CAS  Google Scholar 

  5. I. V. Tikhonov, E. M. Pliss, L. I. Borodin, V. D. Sen’, and T. S. Kuznetsova, Russ. Chem. Bull. 64, 2438 (2015).

    Article  CAS  Google Scholar 

  6. I. V. Tikhonov, E. M. Pliss, L. I. Borodin, and V. D. Sen’, Russ. Chem. Bull. 64, 2869 (2015).

    Article  CAS  Google Scholar 

  7. I. V. Tikhonov, E. M. Pliss, L. I. Borodin, and V. D. Sen’, Russ. Chem. Bull. 65 (12 (2016, in press).

    Google Scholar 

  8. I. V. Tikhonov, V. D. Sen’, L. I. Borodin, et al., J. Phys. Org. Chem. 27, 114 (2014).

    Article  CAS  Google Scholar 

  9. J. M. McCord and I. Fridovich, J. Biol. Chem. 245, 1374 (1970).

    CAS  Google Scholar 

  10. B. Bielski and A. Allen, J. Phys. Chem. 81, 1048 (1977).

    Article  CAS  Google Scholar 

  11. S. Goldstein, G. Merenyi, A. Russo, and A. Samuni, J. Am. Chem. Soc. 125, 789 (2003).

    Article  CAS  Google Scholar 

  12. I. V. Tikhonov, V. D. Sen’, L. I. Borodin, et al., J. Phys. Org. Chem. 28, 17 (2015).

    Article  Google Scholar 

  13. J. S. Olson, D. P. Ballou, G. Palmer, and V. Massey, J. Biol. Chem. 249, 4350 (1974).

    CAS  Google Scholar 

  14. D. M. Stanbury, Adv. Inorg. Chem. 33, 69 (1989).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Demidov Yaroslavl State University, Yaroslavl, 150000, Russia

    I. V. Tikhonov, E. M. Pliss, L. I. Borodin & V. D. Sen’

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. D. Sen’

Authors
  1. I. V. Tikhonov
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  2. E. M. Pliss
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  3. L. I. Borodin
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  4. V. D. Sen’
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Corresponding author

Correspondence to E. M. Pliss.

Additional information

Original Russian Text © I.V. Tikhonov, E.M. Pliss, L.I. Borodin, V.D. Sen’, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 6, pp. 20–23.

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Tikhonov, I.V., Pliss, E.M., Borodin, L.I. et al. Superoxide radicals in the kinetics of nitroxide-inhibited oxidation of methyl linoleate in micelles. Russ. J. Phys. Chem. B 11, 400–402 (2017). https://doi.org/10.1134/S1990793117030253

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  • DOI: https://doi.org/10.1134/S1990793117030253

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