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Russian Journal of Physical Chemistry B

, Volume 9, Issue 4, pp 648–651 | Cite as

Pulsed radiation-induced conductivity of polymers in strong electric fields

  • A. P. TyutnevEmail author
  • B. L. Linetskii
  • A. V. Nikerov
  • V. S. Saenko
Chemical Physics of Polymer Materials

Abstract

A theoretical analysis of the nonlinear field dependence of the pulsed radiation-induced conductivity of polystyrene in strong electric fields is performed. An explanation of the previously uncomprehended phenomenon of the sharp increase in the radiation-induced electrical conductivity in the presence of an electric field with a strength of above 5 × 107 V/m is proposed. This behavior cannot be explained within the framework of Onsager’s theory of the field-assisted thermal production of free charges from generated geminate pairs.

Keywords

charge-carrier transport nanosecond pulse of electrons field dependence of mobility Poole–Frenkel law 

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References

  1. 1.
    A. P. Tyutnev, High Energy Chem. 30 (1), 5 (1996).Google Scholar
  2. 2.
    A. V. Vannikov, V. K. Matveev, V. P. Sichkar’, and A. P. Tyutnev, Radiation Effects in Polymers: Electric Properties (Nauka, Moscow, 1982) [in Russian].Google Scholar
  3. 3.
    A. P. Tyutnev, A. V. Vannikov, G. S. Mingaleev, and V. S. Saenko, Electric Phenomena upon Irradiation of Polymers (Energoatomizdat, Moscow, 1985) [in Russian].Google Scholar
  4. 4.
    A. P. Tyutnev, V. S. Saenko, E. D. Pozhidaev, and N. S. Kostyukov, Dielectric Properties of Polymers in Ionizing Radiation Fields (Nauka, Moscow, 2005) [in Russian].Google Scholar
  5. 5.
    A. Hummel, Adv. Rad. Chem. 4, 1 (1974).Google Scholar
  6. 6.
    A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, A. V. Vannikov, V. S. Saenko, et al., Dokl. Akad. Nauk SSSR 289, 1437 (1986).Google Scholar
  7. 7.
    A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, V. S. Saenko, A. V. Vannikov, et al., Khim. Vys. Energ. 20, 509 (1986).Google Scholar
  8. 8.
    A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, V. S. Saenko, A. V. Vannikov, et al., Acta Polym. 37, 336 (1986).CrossRefGoogle Scholar
  9. 9.
    P. M. Borsenberger and D. S. Weiss, Organic Photoreceptors for Xerography (Marcel Dekker, New York, 1998).Google Scholar
  10. 10.
    H. Bässler, Phys. Status Solidi B 175, 15 (1993).CrossRefGoogle Scholar
  11. 11.
    S. V. Novikov, D. H. Dunlap, V. M. Kenkre, P. E. Parris, and A. V. Vannikov, Phys. Rev. Lett. 81, 4472 (1998).CrossRefGoogle Scholar
  12. 12.
    L. B. Schein, Russ. J. Electrochem. 48, 281 (2012).CrossRefGoogle Scholar
  13. 13.
    S. V. Novikov and A. P. Tyutnev, J. Chem. Phys. 138, 104120 (2013).CrossRefGoogle Scholar
  14. 14.
    R. Sh. Ikhsanov, A. P. Tyutnev, V. S. Saenko, and E. D. Pozhidaev, Russ. J. Phys. Chem. B 2, 309 (2008).CrossRefGoogle Scholar
  15. 15.
    V. R. Nikitenko, H. von Seggern, and H. Bässler, J. Phys.: Condens. Matter 19, 136210 (2007).Google Scholar
  16. 16.
    S. D. Baranovskii, Phys. Status Solidi B 251, 487 (2014).CrossRefGoogle Scholar
  17. 17.
    V. R. Nikitenko, Nonstationary Processes of Transport and Recombination of Charge Carriers in Thin Layers of Organic Materials (NIYaU MIFI, Moscow, 2011) [in Russian].Google Scholar
  18. 18.
    A. P. Tyutnev, R. Sh. Ikhsanov, V. S. Saenko, and E. D. Pozhidaev, Chem. Phys. 404, 88 (2012).CrossRefGoogle Scholar
  19. 19.
    A. P. Tyutnev, D. S. Weiss, D. H. Dunlap, and V. S. Saenko, J. Phys. Chem. C 118, 5150 (2014).CrossRefGoogle Scholar
  20. 20.
    A. P. Tyutnev, R. Sh. Ikhsanov, V. S. Saenko, and E. D. Pozhidaev, Polymer Sci., Ser. A 48, 1196 (2006).CrossRefGoogle Scholar
  21. 21.
    A. P. Tyutnev, Yu. F. Kundina, V. R. Nikitenko, V. S. Saenko, and E. D. Pozhidaev, High Energy Chem. 35, 79 (2001).CrossRefGoogle Scholar
  22. 22.
    A. P. Tyutnev, V. S. Saenko, I. A. Smirnov, and E. D. Pozhidaev, High Energy Chem. 40, 319 (2006).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. P. Tyutnev
    • 1
    Email author
  • B. L. Linetskii
    • 1
  • A. V. Nikerov
    • 1
  • V. S. Saenko
    • 1
  1. 1.National Research University “Higher School of Economics”MoscowRussia

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