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Russian Journal of Physical Chemistry B

, Volume 2, Issue 3, pp 426–430 | Cite as

Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor

  • B. L. Korsunskii
  • N. G. Samoilenko
  • E. V. Deyun
  • A. O. Il’chenko
Jubilee Scientific Conference of the Division of Combustion and Explosion

Abstract

A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless “degree of conversion-temperature” coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates.

Keywords

Exothermic Reaction Thermal Explosion Representative Point Bifurcation Curve Autocatalytic Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK Nauka 2008

Authors and Affiliations

  • B. L. Korsunskii
    • 1
    • 2
  • N. G. Samoilenko
    • 1
  • E. V. Deyun
    • 1
  • A. O. Il’chenko
    • 3
  1. 1.Institute of New Chemical ProblemsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia
  3. 3.Moscow Engineering Physics Institute (Technical University)MoscowRussia

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