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Polymer Science, Series C

, Volume 61, Issue 1, pp 86–101 | Cite as

Synthesis, Molecular, and Gas-Transport Properties of Homopolymers Based on 5-Ethylidene-2-norbornene and 5-Vinyl-2-norbornene

  • E. V. Bermesheva
  • A. I. Wozniak
  • I. L. Borisov
  • N. P. Yevlampieva
  • O. S. Vezo
  • G. O. Karpov
  • M. V. BermeshevEmail author
  • A. F. Asachenko
  • M. A. Topchiy
  • P. S. Gribanov
  • M. S. Nechaev
  • V. V. Volkov
  • E. Sh. Finkelshtein
Article
  • 12 Downloads

Abstract

Using the commercial derivative of norbornene—5-ethylidene-2-norbornene—a series of three isomeric homopolymers with different structure of the backbone is synthesized, and the effect of the chain structure on the gas-transport behavior of polynorbornenes is studied. The gas-transport characteristics of the polymers are presented together with data on the conformation properties of molecules of addition and metathesis polynorbornenes. The effect of the structure of side substituents on the equilibrium rigidity of addition polynorbornenes is confirmed by the example of poly(5-ethylidene-2-norbornene) and poly(5-vinyl-2-norbornene).

Notes

FUNDING

The study of the addition polymerization of bifunctional norbornenes and the characterization of the synthesized polymers were supported by the Russian Science Foundation (project no. 17-19-01595). Metathesis polymerization of 5-vinyl-2-norbornene and the study of properties of polymers based on it was carried out within the framework of the state task for the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • E. V. Bermesheva
    • 1
    • 2
  • A. I. Wozniak
    • 1
  • I. L. Borisov
    • 1
  • N. P. Yevlampieva
    • 3
  • O. S. Vezo
    • 3
  • G. O. Karpov
    • 1
  • M. V. Bermeshev
    • 1
    Email author
  • A. F. Asachenko
    • 1
  • M. A. Topchiy
    • 1
  • P. S. Gribanov
    • 1
  • M. S. Nechaev
    • 1
    • 4
  • V. V. Volkov
    • 1
  • E. Sh. Finkelshtein
    • 1
  1. 1.Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia
  2. 2.Sechenov Moscow State Medical UniversityMoscowRussia
  3. 3.St. Petersburg State UniversitySt. PetersburgRussia
  4. 4.Faculty of Chemistry, Moscow State UniversityMoscowRussia

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