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Polymer Science Series C

, Volume 58, Issue 1, pp 50–61 | Cite as

Polymer composite materials based on thermoset epoxy binders modified with diamond-containing nanofillers

  • T. S. KurkinEmail author
  • E. P. Tikunova
  • A. V. Solopchenko
  • M. Yu. Yablokova
  • A. N. Ozerin
Article

Abstract

Structural features and physicochemical properties of promising diamond-containing modifier fillers for industrial polymers, namely, detonation nanodiamonds and nanodiamond soot, are considered. Experimental results demonstrating the possibility to create prepregs with the use of the carbon fabric 1.5 К and a detonation-diamond soot-modified binder based on the epoxy-resin mixture Epikote828/Epikote154 with an anhydride-type curing agent are presented. The rheological characteristics of the diamond-sootmodified binder remain practically the same after storage for 2 or 3 days at room temperature. The dependence of the glass-transition temperatures of the binders on the content of diamond soot in the concentration range 0.025–0.1 wt % is studied, and the correlation between these results and the mechanical characteristics (breaking strength, flexural strength, and crack resistance) of the cured binders is ascertained. Within the entire range of diamond-soot concentrations, the parameters of gelation are determined and the activation energies of this process are calculated.

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • T. S. Kurkin
    • 1
    Email author
  • E. P. Tikunova
    • 1
  • A. V. Solopchenko
    • 2
  • M. Yu. Yablokova
    • 2
  • A. N. Ozerin
    • 1
  1. 1.Enikolopov Institute of Synthetic Polymer MaterialsRussian Academy of SciencesMoscowRussia
  2. 2.Faculty of ChemistryMoscow State UniversityMoscowRussia

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