Polymer Science, Series B

, Volume 61, Issue 3, pp 387–394 | Cite as

Synthesis and Metathesis Polymerization of Cycloadduct Based on Quadricyclane and Perfluoro-1-octene

  • G. O. Karpov
  • D. S. Bakhtin
  • M. V. BermeshevEmail author
  • I. L. Borisov
  • B. A. Bulgakov
  • V. V. Volkov
  • E. Sh. Finkelstein


Previously undescribed norbornene monomer 3,3,4-trifluoro-4-perfluorohexyltricyclononene-7 is synthesized by the [2+2+2] cycloaddition reaction. The monomer is involved in the ring-opening polymerization metathesis in the presence of the first-generation Grubbs catalyst to give rise to the amorphous, glassy unsaturated polymer. The gas-transport properties of the metathesis polymer is studied, the gas permeability and diffusion coefficients for a wide range of gases (He, H2, O2, N2, CO2, CH4) are determined, and the solubility coefficients of gases in this polymer are calculated.



This work was supported by the Russian Science Foundation, project 17-73-10499.


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • G. O. Karpov
    • 1
  • D. S. Bakhtin
    • 1
  • M. V. Bermeshev
    • 1
    • 2
    Email author
  • I. L. Borisov
    • 1
  • B. A. Bulgakov
    • 1
    • 3
  • V. V. Volkov
    • 1
  • E. Sh. Finkelstein
    • 1
  1. 1.A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesMoscowRussia
  2. 2.D.I. Mendeleev University of Chemical TechnologyMoscowRussia
  3. 3.Faculty of Chemistry, M.V. Lomonosov Moscow State UniversityMoscowRussia

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