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Polymer Science, Series B

, Volume 60, Issue 6, pp 816–824 | Cite as

Preparation of Hybrid Material Based of PANI with SiO2 and Its Adsorption of Phenol from Aqueous Solution

  • A. BelaliaEmail author
  • A. Zehhaf
  • A. Benyoucef
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  • 2 Downloads

Abstract

PANI and PANI-SiO2 were prepared by chemical oxidative polymerization in acidic medium of hydrochloric acid (1 M) using ammonium persulfate as oxidant. The developed adsorbents were characterized using various analytical techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and physical adsorption of gases. To further explore the advantages of these materials for real applications, we investigated the electrochemical properties of these samples electrodes. The efficiency of PANI, SiO2 and PANI-SiO2 for the adsorptive removal of phenol (Ph) from aqueous solutions has been evaluated with respect of several experimental conditions. These latter has to do with the effect of contact time and the effect of pH. The experimental data were analyzed by the Langmuir and Freundlich isotherm models. The Langmuir isotherm fits the experimental data very well due to the homogeneous distribution of active sites onto adsorbents surface. The kinetics study revealed that adsorption of Ph onto three samples follows the pseudo-second order kinetic model.

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References

  1. 1.
    P. J. Collins, M. J. Kotterman, J. A. Field, and A. D. Dobson, Appl. Environ. Microbiol. 62, 4563 (1996).Google Scholar
  2. 2.
    A. Majcherczyk, C. Johannes, and A. Hüttermann, Enzyme Microb. Technol. 22, 335 (1998).CrossRefGoogle Scholar
  3. 3.
    H. Ali, Water, Air Soil Pollut. 213, 251 (2010).CrossRefGoogle Scholar
  4. 4.
    C. Janardanan and V. P. Vinisha, Int. J. Adv. Chem. 2, 6 (2014).Google Scholar
  5. 5.
    R. Ansari, Russ. J. Electrochem. 41, 950 (2005).CrossRefGoogle Scholar
  6. 6.
    G. G. Wallac, G. M. Sprinks, L. K. Magure, and P. Teasdale, Handbook of Conductive Eectroactive Polymers: Intelligent Materials Systems, 2nd ed. (CRC Press, New York, 2003).Google Scholar
  7. 7.
    S. Bhadraa, D. Khastgir, N. K. Singha, and J. H. Lee, Prog. Polym. Sci. 34, 783 (2009).CrossRefGoogle Scholar
  8. 8.
    S. Palaniappan and A. John, Prog. Polym. Sci. 33, 732 (2008).CrossRefGoogle Scholar
  9. 9.
    A. Marican, V. C. Sánchez, A. John, V. F. Laurie, and L. S. Santos, Food Chem. 159, 486 (2014).CrossRefGoogle Scholar
  10. 10.
    L. S. Santos, V. F. Laurie, J. Amalraj, V. C. Sánchez, and F. Nachtigall, US Patent No. 8927042 (2015).Google Scholar
  11. 11.
    P. C. Ashley, M. J. Joseph, and P. V. Mohanan, Food Chem. 127, 1808 (2011).CrossRefGoogle Scholar
  12. 12.
    The New Frontiers of Organic and Composite Nanotechnology, Ed. by V. Erokhin, M. Ram, and Ö. Yavuz, (Elsevier, London, 2008), p. 143.Google Scholar
  13. 13.
    M. Sivakumar and A. A. Gedanken, Synth. Met. 148, 301 (2005).CrossRefGoogle Scholar
  14. 14.
    H. Zengin, W. Zhou, J. Jin, R. Czerw, J. D. W. Smith, and L. Echegoyen, Adv. Mater. 14, 1480 (2002).CrossRefGoogle Scholar
  15. 15.
    N. Qingxin, P. Zengyuan, L. Dawei, Z. Huimin, H. Fenglin, C. Yibing, and W. Qufu, Colloids Surf., A 537, 532 (2018).CrossRefGoogle Scholar
  16. 16.
    J. Stejskal and I. Sapurina, Pure Appl. Chem. 77, 815 (2005).CrossRefGoogle Scholar
  17. 17.
    J. Stejskal, M. Trchová, S. Fedorova, I. Sapurina, and J. Zemek, Langmuir 19, 3013 (2003).CrossRefGoogle Scholar
  18. 18.
    J. Stejskal, O. Quadrat, I. Sapurina, J. Zemek, A. Drelinkiewicz, M. HasikeIvo, and K. J. Prokeš, Eur. Polym. J. 38, 631 (2002).CrossRefGoogle Scholar
  19. 19.
    S. Benyakhou, A. Belmokhtar, A. Zehhaf, and A. Benyoucef, J. Mol. Struct. 1150, 580 (2017).CrossRefGoogle Scholar
  20. 20.
    F. Chouli, I. Radja, E. Morallon, and A. Benyoucef, Polym. Compos. 38, E254 (2017).CrossRefGoogle Scholar
  21. 21.
    S. Benykhlef, A. Bekhoukh, R. Berenguer, A. Benyoucef, and E. Morallon, Colloid Polym. Sci. 294, 1877 (2016).CrossRefGoogle Scholar
  22. 22.
    A. Zehhaf, A. Benyoucef, C. Quijada, S. Taleb, and E. Morallon, Int. J. Environ. Sci. Technol. 12, 595 (2015).CrossRefGoogle Scholar
  23. 23.
    F. J. G. Mateos, I. Moulefera, J. M. Rosas, A. Benyoucef, J. R. Mirasol, and T. Cordero, Catalysts 7, 308 (2017).CrossRefGoogle Scholar
  24. 24.
    V. S. Rao, K. S. Rao, M. N. Rao, and U. S. Bora, Asian J. Biochem. Pharm. Res. 2, 567 (2011).Google Scholar
  25. 25.
    M. Mekhloufi, A. Zehhaf, A. Benyoucef, C. Quijada, and E. Morallon, Environ. Monit. Assess. 185, 10365 (2013).CrossRefGoogle Scholar
  26. 26.
    A. R. Kul and H. Koyunchu, J. Hazard. Mater. 179, 332 (2010).CrossRefGoogle Scholar
  27. 27.
    Y. S. Ho and G. McKay, Process Biochem. 34, 451 (1999).CrossRefGoogle Scholar
  28. 28.
    S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity, 2nd ed. (Academic Press, London, 1982), pp. 3–12.Google Scholar
  29. 29.
    C. G. V. Burgess, D. H. Everett, and S. Nuttall, Pure Appl. Chem. 61, 1845 (1989).CrossRefGoogle Scholar
  30. 30.
    A. S. Kumar, H. Bhandari, C. Sharma, F. Khatoon, and S. K. Dhawan, Polym. Int. 62, 1192 (2013).CrossRefGoogle Scholar
  31. 31.
    K. C. Sajjan, A. S. Roy, A. Parveen, and S. Khasim, J. Mater. Sci.: Mater. Electron. 25, 1237 (2014).Google Scholar
  32. 32.
    Y. G. Wang, H. Q. Li, and Y. Y. Xia, Adv. Mater. 18, 2619 (2006).CrossRefGoogle Scholar
  33. 33.
    C. C. Hu and C. H. Chu, Mater. Chem. Phys. 65, 329 (2000).CrossRefGoogle Scholar
  34. 34.
    M. Wawrzkiewicz and Z. Hubicki, J. Hazard. Mater. 164, 502 (2009).CrossRefGoogle Scholar
  35. 35.
    D. Shao, J. Hu, C. Chen, G. Sheng, X. Ren, and X. Wang, J. Phys. Chem. C 114, 21524 (2010).CrossRefGoogle Scholar
  36. 36.
    J. Zhang, J. Han, M. Wang, and R. Guo, J. Mater. Chem. A 5, 4058 (2017)CrossRefGoogle Scholar
  37. 37.
    I. Azni, The Environmentalist 23, 329 (2003).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Laboratoire de Génie des Procédés et Chimie des SolutionsUniversité de Mustapha Stambouli MascaraMascaraAlgeria

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