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Polymer Science Series B

, Volume 57, Issue 6, pp 560–566 | Cite as

Organosilicon surfactants: Effects of structure on the kinetics of heterophase polymerization of methyl methacrylate and behavior in Langmuir films on the surface of water

  • I. A. Gritskova
  • Yu. N. Malakhova
  • V. M. Kopylov
  • D. I. Shragin
  • E. V. Milushkova
  • A. I. Buzin
  • A. A. EzhovaEmail author
  • A. D. Lukashevich
  • S. M. Levachev
  • N. I. Prokopov
Polymerization

Abstract

The kinetics of methyl methacrylate polymerization in the presence of α,ω-functional polydimethylsiloxanes is investigated. The formation of polymer suspensions with a narrow particle-size distribution is explained by the ability of the surfactants to form strong adsorption layers in the interfacial layers of polymer–monomer particles. This assumption is confirmed by data obtained via the Langmuir method with the use of model systems: thin films of the mentioned organosilicon compounds.

Keywords

Surfactant PMMA PDMS Polymer Science Series Narrow Particle Size Distribution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • I. A. Gritskova
    • 1
  • Yu. N. Malakhova
    • 2
    • 3
  • V. M. Kopylov
    • 2
  • D. I. Shragin
    • 2
  • E. V. Milushkova
    • 1
  • A. I. Buzin
    • 2
  • A. A. Ezhova
    • 1
    Email author
  • A. D. Lukashevich
    • 1
  • S. M. Levachev
    • 4
  • N. I. Prokopov
    • 1
  1. 1.Lomonosov State University of Fine Chemical TechnologyMoscowRussia
  2. 2.Enikolopov Institute of Synthetic Polymer MaterialsRussian Academy of SciencesMoscowRussia
  3. 3.National Research Centre Kurchatov InstituteMoscowRussia
  4. 4.Faculty of ChemistryMoscow State UniversityMoscowRussia

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