Polymer Science Series B

, Volume 56, Issue 2, pp 164–177 | Cite as

Solid-state electrolytes based on ionic network polymers

  • A. S. Shaplov
  • D. O. Ponkratov
  • P. S. Vlasov
  • E. I. Lozinskaya
  • I. A. Malyshkina
  • F. Vidal
  • P. -H. Aubert
  • M. Armand
  • Ya. S. Vygodskii
Polyelectrolytes

Abstract

Interpenetrating and semi-interpenetrating polymer networks are synthesized with the use of cationic and anionic ionic monomers: N-[3-(methacryloyloxy)propyl]-N-methylpyrrolidinium bis(trifluoromethane-sulfonyl)imide, N-[2-(2-(2-(methacryloyloxy)ethoxy)ethoxy)ethyl]-N-methylpyrrolidinium bis(fluorosulfonyl)imide, and (N-butyl-N-methylpyrrolidinium 1-[3-(methacryloyloxy)propylsulfonyl] (trifluoromethanesulfonyl) imide. Their ionic conductivities, electrochemical stabilities, heat resistances, thermal stabilities, and mechanical properties and the swelling of the films in ionic liquid/lithium salt mixtures were studied. The copolymerization of N-[2-(2-(2-(methacryloyloxy)ethoxy)ethoxy)ethyl]-N-methylpyrrolidinium bis(fluorosulfonyl)imide and poly(ethylene glycol dimethacrylate) and poly(ethylene glycol methacrylate) in the presence of butadiene-acrylonitrile rubber and a solution of Li(CF3SO2)2N in N-(methoxymethyl)-N-methylpyrrolidinium bis(fluorosulfonyl)imide yielded a solid-state electrolyte with a set of properties optimum among the studied films: an ionic conductivity of 1.3 × 10−4S/cm (25°C), a tensile strength of 80 kPa, and an elongation at break of 60%.

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • A. S. Shaplov
    • 1
  • D. O. Ponkratov
    • 1
  • P. S. Vlasov
    • 2
  • E. I. Lozinskaya
    • 1
  • I. A. Malyshkina
    • 3
  • F. Vidal
    • 4
  • P. -H. Aubert
    • 4
  • M. Armand
    • 5
  • Ya. S. Vygodskii
    • 1
  1. 1.A.N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  2. 2.Faculty of ChemistrySt. Petersburg State UniversityPetrodvorets, St. PetersburgRussia
  3. 3.Faculty of PhysicsMoscow State UniversityMoscowRussia
  4. 4.Laboratoire de Physicochimie des Polymères et des Interfaces (LPPI)Université de Cergy-PontoiseCergy-Pontoise CEDEXFrance
  5. 5.Laboratoire de Réactivité et Chimie des Solides (LRCS)Université de Picardie Jules Verne, UMR 6007 CNRSAmiensFrance

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