Polymer Science Series B

, Volume 55, Issue 3–4, pp 122–138 | Cite as

Synthesis and properties of polymeric analogs of ionic liquids

  • A. S. ShaplovEmail author
  • D. O. Ponkratov
  • P. S. Vlasov
  • E. I. Lozinskaya
  • L. I. Komarova
  • I. A. Malyshkina
  • F. Vidal
  • G. T. M. Nguyen
  • M. Armand
  • C. Wandrey
  • Ya. S. Vygodskii


A number of methacrylate ionic monomers with different structures and mobilities of ionic centers were synthesized. The free-radical polymerization of these monomers in solution affords high-molecular-mass (M sD = 0.5 to 2.5 × 106) thermally stable (T dec > 170°C) polyelectrolytes or cationic or anionic “polymeric ionic liquids.” The conductivities of polycation- and polyanion-derived coatings are (7.4 × 10−10)−(7.6 × 10−7) and (4.9 × 10−10)-(1.6 × 10−7) S/cm (25°C), respectively. As exemplified by poly(1-[3-(methacryloyloxy)propyl]-3-methylimidazolium bis[(trifluoromethanesulfonyl)imide]), the molecular mass and glasstransition temperature of the polymer affect the ionic conductivity of the film coating. The transition from linear polyelectrolytes to crosslinked systems based on ionic monomers and poly(ethylene glycol dimethacrylate) 750 leads to the formation of elastic films featuring satisfactory strength, reduced glass-transition temperatures (−8 to +15°C), and increased ionic conductivity (up to 3.2 × 10−6 S/cm (25°C)).


Ionic Liquid Ionic Conductivity Polymer Science Series Trifluoromethanesulfonyl Ionic Monomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.
    H. Ohno and K. Ito, Chem. Lett. 27, 751 (1998).CrossRefGoogle Scholar
  2. 2.
    A. S. Shaplov, E. I. Lozinskaya, and Y. S. Vygodskii, in Electrochemical Properties and Applications of Ionic Liquids, Ed. by A. A. J. Torriero and M. J. A. Shiddiky (Novapublishers, New York, 2010).Google Scholar
  3. 3.
    H. Ohno and M. Yoshizawa, Ionic Liquids IIIB: Fundamentals, Progress, Challenges, and Opportunities: Transformations and Processes (American Chemical Society, Washington, 2005).Google Scholar
  4. 4.
    H. Ohno, Macromol. Symp. 249–250, 551 (2007).CrossRefGoogle Scholar
  5. 5.
    M. D. Green and T. E. Long, Polym. Rev. 49, 291 (2009).CrossRefGoogle Scholar
  6. 6.
    O. Green, S. Grubjesic, S. Lee, and M. A. Firestone, Polym. Rev. 49, 339 (2009).CrossRefGoogle Scholar
  7. 7.
    D. Mecerreyes, Prog. Polym. Sci. 36, 1629 (2011).CrossRefGoogle Scholar
  8. 8.
    J. Yuan and M. Antonietti, Polymer 52, 1469 (2011).CrossRefGoogle Scholar
  9. 9.
    P. Wasserscheid and T. Welton, Ionic Liquids in Synthesis (Wiley-VCH, Weinheim, 2007).CrossRefGoogle Scholar
  10. 10.
    J. Zhao, X. Shen, F. Yan, L. Qiu, S. Lee, and B. Sun, J. Mater. Chem. 21, 7326 (2011).CrossRefGoogle Scholar
  11. 11.
    G. B. Appetecchi, G.-T. Kim, M. Montanino, M. Carewska, R. Marcilla, D. Mecerreyes, and I. De Meatza, J. Power Sources 195, 3668 (2010).CrossRefGoogle Scholar
  12. 12.
    B. H. Thomas, G. Shafer, J. J. Ma, M.-H. Tu, and D. D. DesMarteau, J. Fluorine Chem. 125, 1231 (2004).CrossRefGoogle Scholar
  13. 13.
    B. Wu, D. Hu, Y. Kuang, B. Liu, X. Zhang, and J. Chen, Angew. Chem., Int. Ed. Engl. 48, 4751 (2009).CrossRefGoogle Scholar
  14. 14.
    H. L. Ricks-Laskoski and A. W. Snow, J. Am. Chem. Soc. 128, 12402 (2006).CrossRefGoogle Scholar
  15. 15.
    Ya. S. Vygodskii, O. A. Mel’nik, A. S. Shaplov, E. I. Lozinskaya, I. A. Malyshkina, and N. D. Gavrilova, Polymer Science, Ser. A 49, 256 (2007).CrossRefGoogle Scholar
  16. 16.
    Y. S. Vygodskii, A. S. Shaplov, E. I. Lozinskaya, K. A. Lyssenko, D. G. Golovanov, I. A. Malyshkina, N. D. Gavrilova, and M. R. Buchmeiser, Macromol. Chem. Phys. 209, 40 (2008).CrossRefGoogle Scholar
  17. 17.
    M. Yoshizawa and H. Ohno, Chem. Lett. 28, 889 (1999).CrossRefGoogle Scholar
  18. 18.
    A. Lewandowski and A. Swiderska-Mocek, J. Power Sources 194, 601 (2009).CrossRefGoogle Scholar
  19. 19.
    M. Galinski, A. Lewandowski, and I. Stepniak, Electrochim. Acta 51, 5567 (2006).CrossRefGoogle Scholar
  20. 20.
    Electrochemical Aspects of Ionic Liquids, Ed. by H. Ohno (Wiley-Interscience, New York, 2005).Google Scholar
  21. 21.
    A. S. Shaplov, E. I. Lozinskaya, D. O. Ponkratov, I. A. Malyshkina, F. Vidal, P.-H. Aubert, O. V. Okatova, G. M. Pavlov, L. I. Komarova, C. Wandrey, and Y. S. Vygodskii, Electrochim. Acta 57, 74 (2011).CrossRefGoogle Scholar
  22. 22.
    A. S. Shaplov, P. S. Vlasov, E. I. Lozinskaya, D. O. Ponkratov, I. A. Malyshkina, F. Vidal, O. V. Okatova, G. M. Pavlov, C. Wandrey, A. Bhide, M. Schonhoff, and Y. S. Vygodskii, Macromolecules 44, 9792 (2011).CrossRefGoogle Scholar
  23. 23.
    A. S. Shaplov, P. S. Vlasov, M. Armand, E. I. Lozinskaya, D. O. Ponkratov, I. A. Malyshkina, F. Vidal, O. V. Okatova, G. M. Pavlov, C. Wandrey, I. A. Godovikov, and Y. S. Vygodskii, Polym. Chem. 2, 2609 (2011).CrossRefGoogle Scholar
  24. 24.
    J.-M. Tarascon and M. Armand, Nature (London) 414, 359 (2001).CrossRefGoogle Scholar
  25. 25.
    F. M. Gray, Solid Polymer Eelectrolytes: Fundamentals and Technological Applications (Wiley, New York, 1991).Google Scholar
  26. 26.
    M. A. Ratner and D. F. Shriver, Chem. Rev. 88, 109 (1988).CrossRefGoogle Scholar
  27. 27.
    O. A. Mel’nik, A. S. Shaplov, E. I. Lozinskaya, N. A. Popova, M. V. Makarov, L. I. Odinets, K. A. Lysenko, G. I. Timofeeva, I. A. Malyshkina, and Ya. S. Vygodskii, Polymer Science, Ser. B 52, 316 (2010).CrossRefGoogle Scholar
  28. 28.
    M. Hirao, K. Ito-Akita, and H. Ohno, Polym. Adv. Technol. 11, 534 (2000).CrossRefGoogle Scholar
  29. 29.
    H. Chen, J.-H. Choi, D. Salas-De la Cruz, K. I. Winey, and Y. A. Elabd, Macromolecules 42, 4809 (2009).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • A. S. Shaplov
    • 1
    Email author
  • D. O. Ponkratov
    • 1
  • P. S. Vlasov
    • 2
  • E. I. Lozinskaya
    • 1
  • L. I. Komarova
    • 1
  • I. A. Malyshkina
    • 3
  • F. Vidal
    • 4
  • G. T. M. Nguyen
    • 4
  • M. Armand
    • 5
  • C. Wandrey
    • 6
  • Ya. S. Vygodskii
    • 1
  1. 1.A.N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  2. 2.Faculty of ChemistrySt. Petersburg State UniversityPetrodvorets, St. PetersburgRussia
  3. 3.Faculty of PhysicsMoscow State UniversityMoscowRussia
  4. 4.Laboratoire de Physicochimie des Polyméres et des Interfaces (LPPI)Université de Cergy-PontoiseCergy-Pontoise CEDEXFrance
  5. 5.Laboratoire de Médecine Régénérative et de Pharmacobiologie (LMRP)Ecole Polytechnique Fédérale de Lausanne (EPFL)LausanneSwitzerland
  6. 6.Laboratoire de Réactivité et Chimie des Solides (LRCS)Université de Picardie Jules VerneAmiensFrance

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