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Polymer Science Series B

, Volume 55, Issue 3–4, pp 122–138 | Cite as

Synthesis and properties of polymeric analogs of ionic liquids

  • A. S. ShaplovEmail author
  • D. O. Ponkratov
  • P. S. Vlasov
  • E. I. Lozinskaya
  • L. I. Komarova
  • I. A. Malyshkina
  • F. Vidal
  • G. T. M. Nguyen
  • M. Armand
  • C. Wandrey
  • Ya. S. Vygodskii
Synthesis

Abstract

A number of methacrylate ionic monomers with different structures and mobilities of ionic centers were synthesized. The free-radical polymerization of these monomers in solution affords high-molecular-mass (M sD = 0.5 to 2.5 × 106) thermally stable (T dec > 170°C) polyelectrolytes or cationic or anionic “polymeric ionic liquids.” The conductivities of polycation- and polyanion-derived coatings are (7.4 × 10−10)−(7.6 × 10−7) and (4.9 × 10−10)-(1.6 × 10−7) S/cm (25°C), respectively. As exemplified by poly(1-[3-(methacryloyloxy)propyl]-3-methylimidazolium bis[(trifluoromethanesulfonyl)imide]), the molecular mass and glasstransition temperature of the polymer affect the ionic conductivity of the film coating. The transition from linear polyelectrolytes to crosslinked systems based on ionic monomers and poly(ethylene glycol dimethacrylate) 750 leads to the formation of elastic films featuring satisfactory strength, reduced glass-transition temperatures (−8 to +15°C), and increased ionic conductivity (up to 3.2 × 10−6 S/cm (25°C)).

Keywords

Ionic Liquid Ionic Conductivity Polymer Science Series Trifluoromethanesulfonyl Ionic Monomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • A. S. Shaplov
    • 1
    Email author
  • D. O. Ponkratov
    • 1
  • P. S. Vlasov
    • 2
  • E. I. Lozinskaya
    • 1
  • L. I. Komarova
    • 1
  • I. A. Malyshkina
    • 3
  • F. Vidal
    • 4
  • G. T. M. Nguyen
    • 4
  • M. Armand
    • 5
  • C. Wandrey
    • 6
  • Ya. S. Vygodskii
    • 1
  1. 1.A.N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia
  2. 2.Faculty of ChemistrySt. Petersburg State UniversityPetrodvorets, St. PetersburgRussia
  3. 3.Faculty of PhysicsMoscow State UniversityMoscowRussia
  4. 4.Laboratoire de Physicochimie des Polyméres et des Interfaces (LPPI)Université de Cergy-PontoiseCergy-Pontoise CEDEXFrance
  5. 5.Laboratoire de Médecine Régénérative et de Pharmacobiologie (LMRP)Ecole Polytechnique Fédérale de Lausanne (EPFL)LausanneSwitzerland
  6. 6.Laboratoire de Réactivité et Chimie des Solides (LRCS)Université de Picardie Jules VerneAmiensFrance

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