Polymer Science Series B

, Volume 51, Issue 1–2, pp 33–37 | Cite as

Intergel interpolyelectrolyte reaction and synthesis of hybdrid composites based on charged microgels and inorganic nanocrystals



We have studied the interaction between oppositely charged microparticles of polyelectrolyte hydrogels whose low-molecular-mass counterions form insoluble compounds. The intergel polyelectrolyte reaction of such polymers leads to formation of a crystalline compound in the microgel mixture phase. The asprepared samples are composites containing, along with unreacted microgel regions, the interpolyelectrolyte complex comprising the intercrystalline low-molecular-mass compound. It has been shown that both unreacted microgel regions and insoluble compound incorporated into the intergel complex can be involved in chemical modification.


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© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  1. 1.Faculty of ChemistryMoscow State UniversityMoscowRussia

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