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Glass Physics and Chemistry

, Volume 44, Issue 5, pp 440–449 | Cite as

Sol-Gel Synthesis, Thermal Behavior of Nanopowders and Chemical Stability of La1 – xHoxPO4 Ceramic Matrices

  • L. P. Mezentseva
  • A. V. Osipov
  • V. L. Ugolkov
  • A. A. Akatov
  • V. A. Doilnitsyn
  • T. P. Maslennikova
  • A. V. Yakovlev
Article
  • 8 Downloads

Abstract

Nanosized powders of orthophosphates in the LaPO4–HoPO4–H2O system have been synthesized to determine the mutual solubility of LaPO4 · nH2O and HoPO4 · nH2O initial components and to obtain ceramic matrices by sintering them. Formation of hexagonal, monoclinic or tetragonal solid solutions was revealed, and their limits and thermal stability were determined. A series of limited hexagonal LaPO4 · nH2O-based solid solutions was observed within the 0 ≤ x ≤ 0.6 concentration range up to 600°C. Further they transformed to monoclinic LaPO4-based form within the 0 ≤ x ≤ 0.3 concentration range. Solubility of LaPO4 · nH2O and LaPO4 in tetragonal HoPO4nH2O) is lower (≤10 mol %). Specific surface area of La1–xHoxPO4 · nH2O powders was in the range of 90.5–165.0 m2/g depending on x. Leaching rate of La3+ and Ho3+ from La1–xHoxPO4 matrices in nitric acid solution (pH 1–2) was determined to be 10–5–10–2 g/(cm2 day) for both ions.

Keywords

sol-gel La1 – xHoxPO4 · nH2O nanopowders ceramic matrices thermal and chemical stability 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • L. P. Mezentseva
    • 1
  • A. V. Osipov
    • 1
  • V. L. Ugolkov
    • 1
  • A. A. Akatov
    • 2
  • V. A. Doilnitsyn
    • 2
  • T. P. Maslennikova
    • 1
  • A. V. Yakovlev
    • 1
  1. 1.Grebenshchikov Institute of Silicate ChemistryRussian Academy of SciencesSt. PetersburgRussia
  2. 2.Saint-Petersburg State Institute of Technology (Technical University)St. PetersburgRussia

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