Glass Physics and Chemistry

, Volume 41, Issue 2, pp 151–156 | Cite as

Spectral-luminescent properties of trivalent chromium ions in glass of the system K2O-Al2O3-B2O3

  • S. A. Stepanov
  • N. V. Nikonorov
  • V. A. Aseev
  • S. S. Zapalova
Article

Abstract

The spectral-luminescent properties of potassium-aluminoborate glass activated by trivalent chromium ions and subjected to thermal treatment at various temperature and duration regimes are studied. The X-ray-phase studies have shown that by thermal treatment of such potassium-aluminoborate glass a crystalline phase of Al2O3: Cr is evolved. The embedding of chromium ions into the crystalline phase causes changes in the absorption and luminescence spectra.

Keywords

activated glass-ceramics trivalent chromium potassium-aluminoborate glass 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Beall, G.H. and Pinckney, L.R., Nanophase glass-ceramics, J. Am. Ceram. Soc., 1999, vol. 82, no. 1, pp. 5–16.CrossRefGoogle Scholar
  2. 2.
    Ulyashenko, A.M., Nikonorov, N.V., and Przhevuskii, A.K., Forsterite nano-glass-ceramics doped with Cr4+ ions for fiber lasers and amplifiers, Bull. Russ. Acad. Sci.: Phys., 2007, vol. 71, no. 2, pp. 159–163.CrossRefGoogle Scholar
  3. 3.
    Subbotin, K.A., Smirnov, V.A., Zharikov, E.V., Iskhakova, L.D., Senin, V.G., Voronov, V.V., and Shcherbakov, I.A., Nano-glass-ceramics containing chromium-doped LiGaSiO4 crystalline phases, Opt. Mater., 2010, vol. 32, pp. 896–902.CrossRefGoogle Scholar
  4. 4.
    Hamedani Golshan, N., Eftekhari Yekta, B., and Marghussian, V.K., Crystallization and optical properties of a transparent mullite glass ceramic, Opt. Mater., 2012, vol. 34, no. 4, pp. 596–599.CrossRefGoogle Scholar
  5. 5.
    Skorospelova, V.I. and Stepanov, S.A., The behavior of the iron ions in glasses of the K2O-Al2O3-B2O3 system, Izv. Akad. Nauk SSSR, Neorg. Mater., 1974, vol. 10, pp. 1864–1871.Google Scholar
  6. 6.
    Koepke, Cz., Wisniewski, K., Grinberg, M., and Beall, G.H., Excited state absorption in the gahnite glass ceramics and its parent glass doped with chromium, Spectrochim. Acta, Part A, 1998, vol. 54, pp. 1725–1734.CrossRefGoogle Scholar
  7. 7.
    Vasilevskaya, T.N., Kaplyanskii, A.A., Kulinkin, A.B., and Feofilov, S.P., Luminescence of Cr3+ impurity ions in Li2Ge7O15 nanocrystals and clusters embedded in lithium germanate glasses, Phys. Solid State, 2003, vol. 45, no. 5, pp. 961–968.CrossRefGoogle Scholar
  8. 8.
    Kulinkin, A.B., Feofilov, S.P., and Zakharchenya, R.I., Luminescence of impurity 3d and 4f metal ions in different crystalline forms of Al2O3, Phys. Solid State, 2000, vol. 42, no. 5, pp. 857–860.CrossRefGoogle Scholar
  9. 9.
    Kozhina, I.I., Kornilova, E.E., Petrovskii, G.T., and Stepanov, S.A., X-ray diffraction investigation of the R2O-Al2O3-B2O3 system, Vestn. Leningr. Univ., 1983, no. 16, pp. 40–46.Google Scholar
  10. 10.
    Belozerskii, G.N., Kalyamin, A.V., Kornilova, E.E., Petrovskii, G.T., and Stepanov, S.A., The influence of heat treatment on the degree of aggregation of iron ions in potassium aluminoborate glasses, Fiz. Khim. Stekla, 1984, vol. 10, no. 3, pp. 289–295.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • S. A. Stepanov
    • 1
  • N. V. Nikonorov
    • 2
  • V. A. Aseev
    • 2
  • S. S. Zapalova
    • 1
  1. 1.Public CorporationScientific-Research Technological Institute Vavilov VN Center GOI of Optical Material EngineeringSt. PetersburgRussia
  2. 2.University ITMOSt. PetersburgRussia

Personalised recommendations