Glass Physics and Chemistry

, Volume 37, Issue 6, pp 624–628 | Cite as

Effect of the modification of barium titanate on the permittivity of its composites with cyanoethyl ester of polyvinyl alcohol

  • S. V. Myakin
  • V. G. Korsakov
  • T. I. Panova
  • E. A. Sosnov
  • Yu. C. Fomchenkova
  • M. M. Sychov
  • O. A. Shilova
Proceedings of the First All-Russian Conference “Sol-Gel Synthesis and Study of Inorganic Compounds, Hybrid Functional Materials, and Disperse Systems” (St. Petersburg, Russia, November 22–24, 2010)

Abstract

The effect of chemical modification of submicron barium titanate particles by the deposition of MxOy (x = Ti, Co, Ni) oxide layers from aqueous solutions of the corresponding precursors is studied upon the surface properties of modified BaTiO3 particles and dielectric permittivity of organo-inorganic composites obtained by their dispersion in the matrix of cyanoethyl ester of polyvinyl alcohol and useful in electroluminescent light sources. It is shown that a significant increase (by about 25%) of the dielectric permittivity is observed only when adding Nb2O5, in comparison with a similar composite which contains unmodified BaTiO3. A correlation is found between the dielectric permittivity of the organo-inorganic composites and the presence of Brensted neutral and basic centers with pKa = 6−13, localized on the surface of a filler, being capable of interacting with the polymer matrix. It is shown that an increase of the dielectric permittivity upon deposition of niobium oxide on the surface of BaTiO3 is caused by formation of such centers and modification of the surface layer structure of BaTiO3 particles, with transformation of rutile-like Ti-O bonds to anataselike ones.

Keywords

barium titanate organo-inorganic composites compatibility surface modification chemical codeposition high permittivity 

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • S. V. Myakin
    • 1
  • V. G. Korsakov
    • 1
  • T. I. Panova
    • 2
  • E. A. Sosnov
    • 1
  • Yu. C. Fomchenkova
    • 1
  • M. M. Sychov
    • 1
  • O. A. Shilova
    • 2
  1. 1.St. Petersburg State Institute of Technology (Technical University)St. PetersburgRussia
  2. 2.Grebenshchikov Institute of Silicate ChemistryRussian Academy of SciencesSt. PetersburgRussia

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