Abstract
The occurrence, morphology, and composition of rinkite are considered against the background of zoning in the Khibiny pluton. Accessory rinkite is mostly characteristic of foyaite in the outer part of pluton, occurs somewhat less frequently in foyaite and rischorrite in the central part of pluton, even more sparsely in foidolites and apatite–nepheline rocks, and sporadically in fenitized xenoliths of the Lovozero Formation. The largest, up to economic, accumulations of rinkite are related to the pegmatite and hydrothermal veins, which occur in nepheline syenite on both sides of the Main foidolite ring. The composition of rinkite varies throughout the pluton. The Ca, Na, and F contents in accessory rinkite and amorphous products of its alteration progressively increase from foyaite and fenitized basalt of the Lovozero Formation to foidolite, rischorrite, apatite–nepheline rocks, and pegmatite–hydrothermal veins.
Similar content being viewed by others
References
A Classification of Igneous Rocks and Glossary of Terms. Recommendations of the International Union of Geological Sciences, Subcomission oh the Systematics of Igneous Rocks, R.W. Le Maitre et al., Eds., Oxford: Blackwell, 1989; Moscow: Nedra, 1997.
Afanas’ev, M.C., Lovchorrite deposit at the Juksporr, in Khibinskie apatity (Khibiny Apatites), Fersman, A.E., Ed., Leningrad: NIS-NKTP, 1933, vol. 6, pp. 105–107.
Afanas’ev, M.C. and Salie, E.A., Lovchorrite deposit in the Khibiny, in Khibinskie redkie elementy i pirrotiny (Khibiny Rare Elements and Pyrrhotites), Fersman, A.E., Ed., Leningrad: Goskhimtekhizdat, 1933, pp. 69–80.
Arzamastsev, A.A., Arzamastseva, L.V., Travin, A.V., Belyatsky, B.V., Shamatrina, A.M., Antonov, A.V., Larionov, A.N., Rodionov, N.V., and Sergeev, S.A., Duration of formation of magmatic system of polyphase Paleozoic alkaline complexes of the central Kola: U–Pb, Rb–Sr, Ar–Ar Data, Dokl. Earth Sci., 2007, vol. 413, no. 3, pp. 432–436.
Bellezza, M., Merlino, S., and Perchiazzi, N., Mosandrite: structural and crystal-chemical relationships with rinkite, Can. Mineral., 2009, vol. 47, pp. 897–908.
Bohnstedt, E.M., On new minerals of mosandrite group from the Khibiny Tundras, Izv. Akad. Nauk, 1926, pp. 1181–1197.
Borneman-Starynkevich, I.D., Chemical compositions of lovchorrite and chondrikite, in Khibinskie apatity (Khibiny Apatites), Fersman, A.E., Ed., Leningrad: NIS-NKTP, 1933, vol. 6, pp. 114–118.
Camara, F., Sokolova, E., and Hawthorne, C., From structure topology to chemical composition. XII. Titanium silicates: the crystal chemistry of rinkite, Na2Ca4REETi(Si2O7)2OF3, Mineral. Mag., 2011, vol. 75, no.6, 2755–2774.
Cristiansen, C.C. and Ronsbo, J.G., On the structural relationship between gotzenite and rinkite, Neues Jahrb. Mineral. Monatsh., 2000, pp. 496–506.
Fersman, A., Bonshtedt, E., Gutkova, N., Kostyleva, E., Kupletsky, B., and Labuntsov, A., Description of deposits in the Khibiny and Lovozeto Tundras, in Khibinskie i Lovozerskie tundry (Khibiny and Lovozero Tundras), Fersman, A.E., Ed., Moscow: NTU VSNKh, 1928, pp. 206–212.
Galakhov, A.V., The Lovchorrite-bearing veins in the eastern part of Mount Eveslogchorr in the Khibiny, in Voprosy geologii i mineralogii Kol’skogo poluostrova (Geology and Mineralogy of Kola Peninsula), Moscow: AN SSSR, 1958, issue 1, pp. 165–180.
Goryainov, P.M., Ivanyuk, G.Yu., and Kalashnikov, A.O., Topography formation as an element of lithospheric selforganization, Russian Geol. Geophys., 2013, vol. 54, no. 9, pp. 1071–1082.
Gutkova, N.N., Zone of lovchorrite and rinkite deposits of the Khibiny Tundras, in Khibinskie redkie elementy i pirrotiny (Khibiny Rare Elements and Pyrrhotites), Fersman, A.E., Ed., Leningrad: Goskhimtekhizdat, 1933, pp. 60–69.
Gutkova, N.N., Mineralogy of Mount Juksporr, in Materialy po petrografii i geokhimii Kol’skogo poluostrova (Petrography and Geochemistry of Kola Peninsula), Leningrad: AN SSSR, 1934, pp. 7–108.
Ivanyuk, G.Yu., Goryainov, P.M., Pakhomovsky Ya.A., Konopleva, G., Yakovenchuk, V.N., Bazai, A.V., and Kalashnikov, A.O., Samoorganizatsiya rudnykh kompleksov. Sinergeticheskie printsipy prognozirovaniya i poiskov mestorozhdenii poleznykh iskopaemykh (Self-Organization of Ore Complexes. Synergetic Principles of Forecasting and Prospecting of Mineral Resources), Moscow: GEOKARTGEOS, 2009.
Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Konopleva, N.G., Yakovenchuk, V.N., Menshikov, Yu.P., and Mikhailova, Yu.A., Spinel-group minerals in rocks of the Khibiny Alkaline Pluton, Kola Peninsula, Geol. Ore Deposits, 2007, vol. 49, spec. issue 7 (Zapiski Russian Mineral. Soc.), pp. 599–606.
Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Konopleva, N.G., Kalashnikov, A.O., Korchak, Yu.A., Selivanova, E.A., and Yakovenchuk, V.N., Rock-forming feldspar of the Khibiny Alkaline Pluton, Kola Peninsula, Russia, Geol. Ore Deposits, 2010, vol. 52, spec. issue 8 (Zapiski Russian Mineral. Soc.), pp. 736–747.
Ivanyuk, G.Yu., Yakovenchuk, V.N., and Pakhomovsky, Ya.A., Where are new minerals hiding? The main features of rare mineral localization within alkaline massifs, in Minerals as Advanced Materials II, S.V. Krivovichev, Ed., Berlin: Springer, 2012a, pp. 13–24.
Ivanyuk, G., Yakovenchuk, V., Pakhomovsky, Ya., Konoplyova, N., Kalashnikov, A., Mikhailova, J., and Goryainov, P., Self-Organization of the Khibiny Alkaline Massif (Kola Peninsula, Russia) in Earth Sciences, Imran Ahmad Dar, Ed., INTECH, 2012b, pp. 131–156.
Konopleva, N.G., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Yakovenchuk, V.N., Men’shikov, Yu.P., and Korchak, Yu.A., Amphiboles of the Khibiny Alkaline Pluton, Kola Peninsula, Russia, Geol. Ore Deposits, 2008, vol. 50, spec. issue 8 (Zapiski Russian Mineral. Soc.), pp. 720–731.
Konopleva, N.G., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Yakovenchuk, V.N., Kalashnikov, A.O., Mikhailova, Yu.A., and Goryainov, P.M., Resource Potential of the Kola REE province, in Geologiya i strategicheskie poleznye iskopaemye Kol’skogo regiona (Geology and Strategic Mineral Resources of the Kola Region), Apatity: K&M, 2012, pp. 266–270.
Konopleva, N.G., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Mikhailova, Yu.A., Yakovenchuk, V.N., and Kalashnikov, A.O., Rinkite mineralization of the Khibiny alkaline pluton, in Geologiya i strategicheskie poleznye iskopaemye Kol’skogo regiona (Geology and Strategic Mineral Resources of the Kola Region), Apatity: K&M, 2012, pp. 202–205.
Konopleva, N.G., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Yakovenchuk, V.N., and Mikhailova, Yu.A., Typomorfism of fluorapatite in the Khibiny Alkaline Pluton, Kola Peninsula, Geol. Ore Deposits, 2014, vol. 56, spec. issue 7 (Zapiski Russian Mineral. Soc.), pp. 576–588.
Korchak, Yu.A., Men’shikov, Yu.P., Pakhomovsky, Ya.A., Yakovenchuk, V.N., and Ivanyuk, G.Yu., Trap Formation of the Kola Peninsula, Petrology, 2011, vol. 19, no. 1, pp. 87–101.
Kostyleva-Labuntsova, E.E., Borutsky, B.E., Sokolova, M.N., and Shlyukova, Z.V., Dorfman, M.D., Dudkin, O.B., and Kozyreva L.V., Mineralogiya Khibinskogo massiva (Mineralogy of the Khibiny pluton), Moscow: Nauka, 1978, vol. 2: Minerals.
Kramm, U. and Kogarko, L.N., Nd and Sr isotope signatures of the Khibiny and Lovozero agpaitic centres, Kola alkaline province, Russia, Lithos, 1994, vol. 32, pp. 225–242.
Mikhailova, Yu.A., Konopleva, N.G., Yakovenchuk, V.N., Ivanyuk, G.Yu., Men’shikov, Yu.P., and Pakhomovskii, Ya.A., Corundum-group minerals in rocks of the Khibiny Alkaline Pluton, Kola Peninsula, Geol. Ore Deposits, 2007, vol. 49, spec. issue 7 (Zapiski Russian Mineral. Soc.), pp. 590–598.
Mikhalev, D.N., The Juksporr lovchorrite deposit in the Khibiny, in Sbornik geologicheskikh rabot (Collection of Geological Works), Kupletsky, B.M, Ed., Moscow: AN SSSR, 1937, pp. 5–57.
Ozhinsky, I.S., Lovchorrite deposits in the outer belt of Khibiny Tundras, in Khibinskie apatity (Khibiny Apatites), Fersman, A.E., Ed., Leningrad: NIS-NKTP, 1933, vol. 6, pp. 107–111.
Ozhinsky, I.S., Lovchorrite–rinkite deposits in the outer belt of the Khibiny, Zapiski (Proc. Russian Miner. Soc.), 1935, vol. 64, no. 2, pp. 355–415.
Semenov, E.I., Mineralogiya redkikh zemel (Mineralogy of Rare Earths), Moscow: AN SSSR, 1963.
Shablinsky, G.N., Deep structure of the Khibiny and the Loxozero plutons, Trudy Leningrad. Ob–va Estestvoispyt., 1963, vol. 74, pp. 41–43.
Slepnev, Yu.S., Rinkite-group minerals, Izv. AN SSSR, Ser. Geol., 1957, no. 3, pp. 63–75.
Slepnev, Yu.S., Lovchorrite–Rinkite Pegmatites, in Trudy IMGRE AN SSSR, 1962, no. 13, pp. 1–115.
Snyatkova, O.L., Mikhnyak, N.K., Markitakhina, T.M., Pronyagin, N.I., Chapin, V.A., Zhelezova, N.N., Durakova, A.B., Evstaf’ev, A.S., Podurushin, V.F., and Kalinkin, M.M., Otchet o rezul’tatakh geologicheskogo doizucheniya i geokhimicheskikh poiskov na redkie metally i apatit masshtaba 1: 50000, provedennykh v predelakh Khibinskogo massiva i ego obramleniya za 1979–1983 gg. (Report on Results of Geological Follow-up and Geochemical Exploration for Rare Metals and Apatite on a Scale of 1: 50000 Carried out in the Khibiny Pluton and Its Framework during 1979–1983), Apatity: Murmansk Branch of FGU, TFI of Northwestern Federal Okrug, 1983, vol. 1, part 1.
Sokolova, E., From structure topology to chemical composition. I. Structural hierarchy and stereochemistry in titanium disilicate minerals, Can. Mineral., 2006, vol. 44, pp. 1273–1330.
Sokolova, E. and Camara, F., From structure topology to chemical composition. VIII. Titanium silicates: The crystal structure and crystal chemistry of mosandrite from type locality of Laven (Skadon), Lan-Gesundsfjorden, Larvik, Vestfold, Norway, Mineral. Mag., 2008, vol. 72, pp. 887–897.
Vlodavets, N.I. and Kagan, B.I., Lovchorrite, in Mineraly Khibinskikh i Lovozerskikh tundr (Minerals of Khibiny and Lovozero Tundras), AN SSSR, 1937, pp. 508–512.
Whitney, D.L. and Evans, B.W., Abbreviations for names of rock-forming minerals, Am. Mineral., 2010, vol. 95, pp. 185–187.
Yakovenchuk, V.N., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., and Menshikov, Yu.P., Mineraly Khibinskogo massiva (Minerals from the Khibiny Pluton), Moscow: Zemlya, 1999.
Yakovenchuk, V.N., Ivanyuk, G.Yu., and Pakhomovsky, Ya.A., Menshikov Yu.P., Khibiny, Wall, F., Ed., Apatity: Laplandia Minerals, 2005.
Yakovenchuk, V.N., Ivanyuk, G.Yu., Pakhomovsky, Ya.A., Menshikov, Yu.P., Konopleva, N.G., and Korchak, Yu.A., Pyroxenes of the Khibiny Alkaline Pluton, Kola Peninsula, Geol. Ore Deposits, 2008, vol. 50, spec. issue 8 (Zapiski Russian Mineral. Soc.), pp. 732–745.
Yakovenchuk, V.N., Ivanyuk, G.Yu., Konopleva, N.G., Korchak, Yu.A., and Pakhomovsky, Ya.A., Nepheline from the Khibiny Alkaline Pluton, Kola Peninsula, Zapiski Russian Mineral. Soc., 2010, vol. 139, no. 2, pp. 80–91.
Yakovenchuk, V.N., Ivanyuk, G.Yu., Krivovichev, S.V., Pakhomovsky, Ya.A., Selivanova, E.A., Zhitova, E.S., Mikhailova, Yu.A., and Kalashnikova, G.O., Carbonates–titanosilicates of the tundrite-(Se)–chilmanite-(Se) from alkaline pegmatite in fenitized amphibolite at Mt. Chilmana, in Geologiya i strategicheskie poleznye iskopaemye Kol’skogo regiona (Geology and Strategic Mineral Resources of the Kola Region), Apatity: K&M, 2013, pp. 226–228.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.G. Konopleva, G.Yu. Ivanyuk, Ya.A. Pakhomovsky, V.N. Yakovenchuk, Yu.A. Mikhailova, E.A. Selivanova, 2014, published in Zapiski Rossiiskogo Mineralogicheskogo Obshchestva, 2014, No. 5, pp. 97–113.
Rights and permissions
About this article
Cite this article
Konopleva, N.G., Ivanyuk, G.Y., Pakhomovsky, Y.A. et al. Typochemistry of rinkite and products of its alteration in the Khibiny Alkaline pluton, Kola Peninsula. Geol. Ore Deposits 57, 614–625 (2015). https://doi.org/10.1134/S1075701515070065
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1075701515070065