Abstract
The reaction of 1,4-dichlorobut-2-yne with propane-1,3-dithiolate was carried out for the first time. A mixture of cyclic (2-vinyl-1,4-dithiepan-2-ene) and linear (5,10-dithiatridec-1,12-diyne-3,10-diene) products was synthesized, in 30 and 15% yields, respectively.
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References
Perin, G., Lenardao, E.J., Jacob, R.G., and Panatiere, R.B., Chem. Rev., 2009, vol. 109, p. 1277. https://doi.org/10.1021/cr8004394
Levanova, E.P., Vahrina, V.S., Grabel’nykh, V.A., Rozentsveig, I.B., Russavskaya, N.V., Albanov, A.I., Klyba, L.V., and Korchevin, N.A., Russ. Chem. Bull., 2015, vol. 64, p. 2083. https://doi.org/10.1007/slll72-015-1121-l
Levanova, E.P., Grabel’nykh, V.A., Vahrina, V.S., Albanov, A.I., Klyba, L.V., Russavskaya, N.V., Korchevin, N.A., and Rozentsveig, L.B., J. Sulfur Chem., 2014, vol 35, p. 179. https://doi.org/10.1080/17415993.2013.849704
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The work was performed using the equipment of the Baikal Analytical Center for Collective Use, Siberian Branch, Russian Academy of Sciences.
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Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 11, pp. 1789–1791.
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Nikonova, V.S., Grabel’nykh, V.A., Russavskaya, N.V. et al. Synthesis of Highly Unsaturated Organic Sulfur Compounds from 1,4-Dichlorobut-2-yne and Propane-1,3-dithiolate. Russ J Org Chem 55, 1800–1801 (2019). https://doi.org/10.1134/S1070428019110241
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DOI: https://doi.org/10.1134/S1070428019110241