Russian Journal of Organic Chemistry

, Volume 55, Issue 1, pp 124–127 | Cite as

Convenient Synthesis of Polyfunctional Diphosphonium Salts Based on 2-Methyl-1,4-naphthoquinone

  • N. R. KhasiyatullinaEmail author
  • V. F. Mironov
Short Communications


An efficient procedure has been proposed for the synthesis of new 1,4-dioxo- and 1,4-dihydroxynaphthyl-substituted diphosphonium salts from 2-methyl-1,4-naphthoquinone and alkane-α,ω-diylbis(diphenylphosphonium) bis(trifluoroacetates). The structure of the products was determined by NMR spectroscopy.


tertiary phosphines PH-phosphonium salts diphosphonium salts 2-methyl-1,4-naphthoquinone trifluoroacetic acid 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Suin, S., Shrivastava, N.K., Maiti, S., and Khatua, B.B., Appl. Clay Sci., 2014, vol. 95, p. 182. doi CrossRefGoogle Scholar
  2. 2.
    Gómez, R., Segura, J.L., and Martin, N., J. Org. Chem., 2000, vol. 65, no. 22, p. 7566. doi CrossRefGoogle Scholar
  3. 3.
    Beletskaya, I.P. and Kazankova, M.A., Russ. J. Org. Chem., 2002, vol. 38, no. 10, p. 1391. doi CrossRefGoogle Scholar
  4. 4.
    Organophosphorus Chemistry, Allen, D.W. and Tebby, J.S., Eds., Cambridge UK: Roy. Soc. Chem., 2003, vol. 33. doi
  5. 5.
    Arisawa, M. and Yamaguchi, M., Recent Developments in Carbocation and Onium Ion Chemistry (ACS Symposium Series, vol. 965), Laali, K.K., Ed., Washington DC: Am. Chem. Soc., 2007, chap. 22, p. 477. doi CrossRefGoogle Scholar
  6. 6.
    Mironov, V.F., Karaseva, A.N., Nizamov, I.S., Kedrov, I.S., and Konovalov, A.I., Russ. J. Org. Chem., 2004, vol. 40, no. 6, p. 910. doi CrossRefGoogle Scholar
  7. 7.
    Tsepaeva, O.V., Nemtarev, A.V., and Mironov, V.F., Russ. J. Org. Chem., 2017, vol. 53, no. 4, p. 621. doi CrossRefGoogle Scholar
  8. 8.
    Khasiyatullina, N.R., Vazykhova, A.M., Mironov, V.F., Krivolapov, D.B., Voronina, Yu.K., Voloshina, A.D., Kulik, N.V., and Strobykina, A.S., Mendeleev Commun., 2017, vol. 27, no. 2, p. 134. doi CrossRefGoogle Scholar
  9. 9.
    Bogdanov, A.V., Mironov, V.F., Khasiyatullina, N.R., Krivolapov, D.B., Litvinov, I.A., and Konovalov, A.I., Phosphorus, Sulfur Silicon Relat. Elem., 2008, vol. 183, nos. 2–3, p. 571. doi CrossRefGoogle Scholar
  10. 10.
    Khasiyatullina, N.R. and Mironov, V.F., Russ. J. Org. Chem., 2015, vol. 51, no. 9, p. 1343. doi CrossRefGoogle Scholar
  11. 11.
    Mironov, V.F., Khasiyatullina, N.R., and Krivolapov, D.B., Tetrahedron Lett., 2015, vol. 56, no. 51, p. 7132. doi CrossRefGoogle Scholar
  12. 12.
    Fong, T.P., Forde, C.E., Lough, A.J., Morris, P., Rigo, A.J., Rocchini, P.E., and Stephan, T., J. Chem. Soc., Dalton Trans, 1999, p. 4475. doi Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific CenterRussian Academy of SciencesKazan, TatarstanRussia

Personalised recommendations