Russian Journal of Organic Chemistry

, Volume 54, Issue 11, pp 1728–1730 | Cite as

Synthesis of 1-, 2-Methoxy-, 1,3-Dimethoxyadamantanes And 1-, 4-Methoxydiadamantanes by Reaction of Adamantyl and Diadamantyl Halides with Dimethyl Carbonate in the Presence of Zeolite Catalysts

  • R. I. Khusnutdinov
  • N. A. Shchadneva
  • Yu. Yu. MayakovaEmail author
Short Communications


1-, 2-Methoxy-, 1,3-dimethoxyadamantane, and 1-, 4-methoxydiadamantane were prepared by the reaction of adamantyl and diadamantyl halides with dimethyl carbonate in the presence of zeolite catalysts NiHY or FeHY free of binders. Optimum ratio of catalysts and reagents were found and the reaction conditions for the selective synthesis of methoxyadamantanoids were developed.


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • R. I. Khusnutdinov
    • 1
  • N. A. Shchadneva
    • 1
  • Yu. Yu. Mayakova
    • 1
    Email author
  1. 1.Institute of Petrochemistry and Catalysis of the Russian Academy of ScientistsUfa, BashkortostanRussia

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