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Russian Journal of Organic Chemistry

, Volume 54, Issue 10, pp 1579–1582 | Cite as

Synthesis of meta-Carboranyl-(S)-homocysteine Sulfoxide

  • D. A. GruzdevEmail author
  • V. O. Ustinova
  • G. L. Levit
  • V. A. Ol’shevskaya
  • V. P. Krasnov
Short Communications
  • 9 Downloads

Abstract

New (S)-homocysteine derivatives containing a meta-carborane fragment were synthesized. m-Carboranyl-(S)-homocysteine sulfoxide was obtained as a mixture of diastereoisomers. The reduction of the side-chain carboxy group of N-tert-butoxycarbonyl-(S)-aspartic acid α-tert-butyl ester with sodium tetrahydridoborate was not accompanied by racemization.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • D. A. Gruzdev
    • 1
    Email author
  • V. O. Ustinova
    • 1
  • G. L. Levit
    • 1
  • V. A. Ol’shevskaya
    • 2
  • V. P. Krasnov
    • 1
  1. 1.Postovskii Institute of Organic Synthesis, Ural BranchRussian Academy of SciencesYekaterinburgRussia
  2. 2.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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