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Russian Journal of Organic Chemistry

, Volume 54, Issue 8, pp 1122–1126 | Cite as

Hydroxylamine Reactions with Peroxide Products of Alkenes Ozonolysis

  • Yu. V. Legostaeva
  • L. R. Garifullina
  • I. S. Nazarov
  • N. M. Ishmuratova
  • G. Yu. Ishmuratov
Article
  • 18 Downloads

Abstract

Reactions were studied of peroxide ozonolysis products obtained from linear and cyclic alkenes with hydroxylamine prepared in situ from NH2OH·HCl by hydrogen chloride neutralization with sodium acetate. A one-pot reactions sequence was performed: alkene oxidation with ozone → reduction to a carbonyl compound with hydroxylamine → condensation of the carbonyl compound with hydroxylamine providing a possibility of direct transformation of alkenes in keto- and aldoximes excluding the stage of preparation and isolation of the carbonyl compound.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Yu. V. Legostaeva
    • 1
  • L. R. Garifullina
    • 1
  • I. S. Nazarov
    • 1
  • N. M. Ishmuratova
    • 1
  • G. Yu. Ishmuratov
    • 1
  1. 1.Ufa Institute of ChemistryRussian Academy of SciencesUfa, BashkortostanRussia

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