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Russian Journal of Organic Chemistry

, Volume 54, Issue 4, pp 545–553 | Cite as

Reaction of Perfluorobenzocyclobutene with Excess Pentafluorobenzene in SbF5

  • T. V. MezhenkovaEmail author
  • V. R. Sinyakov
  • V. M. Karpov
  • Ya. V. Zonov
  • Yu. V. Gatilov
  • V. E. Platonov
Review
  • 26 Downloads

Abstract

The reaction of perfluorobenzocyclobutene with excess pentafluorobenzene in SbF5, followed by hydrolysis, gave a mixture of perfluoro-1,3,3-triphenyl-1,3-dihydro-2-benzofuran-1-ol, perfluoro-1,1,2-triphenylbenzocyclobuten- 5-one, and perfluoro-4-(2,2-diphenylbenzocyclobuten-1-ylidene)cyclohexa-2,5-dien-1- one. When the reaction mixture was treated for a long time with Olah’s reagent (HF–pyridine), isomeric perfluoro-9,10-diphenyl-1,4-, -1,10-, -2,9-, and -9,10-dihydroanthracenes were formed and were converted to perfluoro-9,10-diphenylanthracene by the action of SbF5.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • T. V. Mezhenkova
    • 1
    Email author
  • V. R. Sinyakov
    • 1
  • V. M. Karpov
    • 1
  • Ya. V. Zonov
    • 1
    • 2
  • Yu. V. Gatilov
    • 1
    • 2
  • V. E. Platonov
    • 1
  1. 1.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia

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