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Russian Journal of Organic Chemistry

, Volume 54, Issue 3, pp 503–505 | Cite as

Reaction of Potassium 1,1,3,3-Tetracyano-2-(2,2-dimethylpropanoyl)propenide with 2-Sulfanylethanol

  • A. A. Grigor’ev
  • S. V. Karpov
  • O. E. Nasakin
  • V. A. Tafeenko
  • O. V. Kayukova
  • Ya. S. KayukovEmail author
Short Communications
  • 24 Downloads

Abstract

The reaction of potassium 2-(2,2-dimethylpropanoyl)-1,1,3,3-tetracyanopropenide with an equimolar amount of 2-sulfanylethanol afforded 2-{5-amino-2-(tert-butyl)-4-cyano-2-[(2-hydroxyethyl)sulfanyl]- 2,3-dihydrofuran-3-ylidene}propanedinitrile, whereas 4-amino-1-(tert-butyl)-1,6-bis[(2-hydroxyethyl)- sulfanyl]-3-imino-1,3-dihydrofuro[3,4-c]pyridine-7-carbonitrile was obtained in the reaction with excess 2-sulfanylethanol.

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References

  1. 1.
    Karpov, S.V., Grigor’ev, A.A., Kayukov, Ya.S., Karpova, I.V., Nasakin, O.E., and Tafeenko, V.A., J. Org. Chem. 2016, vol. 81, p. 6402.CrossRefPubMedGoogle Scholar
  2. 2.
    Grigor’ev, A.A., Karpov, S.V., Kayukov, Ya.S., Belikov, M.Y., and Nasakin, O.E., Tetrahedron Lett., 2015, vol. 56, p. 6279.CrossRefGoogle Scholar
  3. 3.
    Grigor’ev, A.A., Karpov, S.V., Kayukov, Ya.S., Nasakin, O.E., Gracheva, Yu.A., and Tafeenko, V.A., Chem. Heterocycl. Compd., 2017, vol. 53, no. 2, p.230.CrossRefGoogle Scholar
  4. 4.
    Kayukov, Ya.S., Karpov, S.V., Grigor’ev, A.A., Nikiforova, A.L., Nasakin, O.E., Shchegravina, E.S., Kayukova, O.V., and Tafeenko, V.A., Chem. Heterocycl. Compd., 2017, vol. 53, no. 5, p.568.CrossRefGoogle Scholar
  5. 5.
    Karpov, S.V., Kayukov, Ya.S., Bardasov, I.N., Ershov, O.V., Nasakin, O.E., and Kayukova, O.V., Russ. J. Org. Chem., 2011, vol. 47, p. 1161.CrossRefGoogle Scholar
  6. 6.
    Grigor’ev, A.A., Karpov, S.V., Kayukov, Ya.S., Nasakin, O.E., and Tafeenko, V.A., Synlett, 2015, vol. 26, p. 2313.CrossRefGoogle Scholar
  7. 7.
    Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, p.112.CrossRefGoogle Scholar
  8. 8.
    Brandenburg, K., DIAMOND, Bonn, Germany: Crystal Impact, 2000.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. A. Grigor’ev
    • 1
  • S. V. Karpov
    • 1
  • O. E. Nasakin
    • 1
  • V. A. Tafeenko
    • 2
  • O. V. Kayukova
    • 3
  • Ya. S. Kayukov
    • 1
    Email author
  1. 1.I.N. Ul’yanov Chuvash State UniversityCheboksaryRussia
  2. 2.Faculty of ChemistryMoscow State UniversityMoscowRussia
  3. 3.Chuvash State Agricultural AcademyCheboksaryRussia

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