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Russian Journal of Organic Chemistry

, Volume 53, Issue 12, pp 1884–1886 | Cite as

Reaction of 1-(tetracyanocyclopropyl)alkanones with sodium and potassium hydroxides

  • Ya. S. Kayukov
  • A. A. Grigor’ev
  • S. V. Karpov
  • Yu. A. Gracheva
  • O. V. KayukovaEmail author
Short Communications
  • 24 Downloads

Abstract

Enolizable 1-(tetracyanocyclopropyl)alkanones reacted with aqueous alkali metal hydroxides to give, depending on the alkali concentration, 2-(5-amino-2-alkylidene-4-cyano-2,3-dihydrofuran-3-ylidene)-propanedinitriles or 2-(4-alkyl-3-amino-2-cyano-5-oxo-cyclopent-2-en-1-ylidene)propanedinitriles.

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References

  1. 1.
    Karpov, S.V., Grigor’ev, A.A., Kayukov, Ya.S., Karpova, I.V., Nasakin, O.E., and Tafeenko, V.A., J. Org. Chem. 2016, vol. 81, p. 6402.CrossRefGoogle Scholar
  2. 2.
    Kayukov, Ya.S., Karpov, S.V., Bardasov, I.N., Ershov, O.V., Belikov, M.Yu., Nasakin, O.E., and Kayukova, O.V., Russ. J. Org. Chem., 2012, vol. 48, p. 491.CrossRefGoogle Scholar
  3. 3.
    Grigor’ev, A.A., Karpov, S.V., Kayukov, Y.S., Nasakin, O.E., Gracheva, I.A., and Tafeenko, V.A., Chem. Heterocycl. Compd., 2017, vol. 53, p. 230.CrossRefGoogle Scholar
  4. 4.
    Kayukov, Ya.S., Karpov, S.V., Bardasov, I.N., Kayukova, O.V., Ershov, O.V., and Nasakin, O.E., Russ. J. Org. Chem., 2012, vol. 48, p. 1107.CrossRefGoogle Scholar
  5. 5.
    Kayukov, Ya.S., Bardasov, I.N., Kayukova, O.V., Ershov, O.V., and Nasakin, O.E., Russ. J. Org. Chem., 2010, vol. 46, p. 1266.CrossRefGoogle Scholar
  6. 6.
    Kayukov, Ya.S., Bardasov, I.N., Karpov, S.V., Ershov, O.V., Nasakin, O.E., Kayukova, O.V., and Tafeenko, V.A., Russ. J. Org. Chem., 2012, vol. 48, p. 1447.CrossRefGoogle Scholar
  7. 7.
    Kayukov, Ya.S., Karpov, S.V., Kayukova, O.V., Ershov, O.V., and Nasakin, O.E., Russ. J. Org. Chem., 2014, vol. 50, p. 1097.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • Ya. S. Kayukov
    • 1
  • A. A. Grigor’ev
    • 1
  • S. V. Karpov
    • 1
  • Yu. A. Gracheva
    • 2
  • O. V. Kayukova
    • 3
    Email author
  1. 1.I.N. Ul’yanov Chuvash State UniversityCheboksaryRussia
  2. 2.Lobachevsky State University of Nizhny NovgorodNizhny NovgorodRussia
  3. 3.Chuvash State Agricultural AcademyCheboksaryRussia

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