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Russian Journal of Organic Chemistry

, Volume 50, Issue 4, pp 552–558 | Cite as

Synthesis of chromophoric crown-containing styryl derivative of terthiophene and its complexation with octane-1,8-diaminium diperchlorate

  • E. V. LukovskayaEmail author
  • A. A. Kosmacheva
  • O. A. Fedorova
  • A. A. Bobyleva
  • A. V. Dolganov
  • N. E. Shepel’
  • Yu. V. Fedorov
  • V. V. Novikov
  • A. V. Anisimov
Article

Abstract

2,2′: 5′,2″-Terthiophene derivative containing benzo-18-crown-6 fragments linked through ethene spacers was synthesized, and its complexation with octane-1,8-diaminium diperchlorate in acetonitrile was studied by spectrophotometric titration, 1H NMR, and mass spectrometry. The 1: 1 stoichiometry of the complex was confirmed by mass spectrometry, and its structure was proposed on the basis of the 1H NMR data.

Keywords

Thiophene Crown Ether Spectrophotometric Titration Triethyl Phosphite Anti Conformer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Horowitz, G., Fichou, D., Peng, X., Xu, Z., and Garnier, F., Solid State Commun., 1989, vol. 72, p. 381.CrossRefGoogle Scholar
  2. 2.
    Geiger, F., Stoldt, M., Schweizer, H., Bauerle, P., and Umbach, E., Adv. Mater. (Weinheim, Ger.), 1993, vol. 5, p. 922.CrossRefGoogle Scholar
  3. 3.
    Noma, N., Tsuzuki, T., and Shirota, Y., Adv. Mater. (Weinheim, Ger.), 1995, vol. 7, p. 647.CrossRefGoogle Scholar
  4. 4.
    Kumar, A., Welsh, D.M., Morvant, M.C., Piroux, F., Abboud, K.A., and Reynolds, J.R., Chem. Mater., 1998, vol. 10, p. 896.CrossRefGoogle Scholar
  5. 5.
    Lukovskaya, E., Bobylyova, A., Fedorova, O., Fedorov, Yu., Kardashev, S., Maksimov, A., Anisimov, A., Maurel, F., Marmois, E., Jonusauskas, G., Didane, Y., Brisset, H., and Fages, F., Synth. Met., 2007, vol. 157, p. 885.CrossRefGoogle Scholar
  6. 6.
    Fedorova, O., Lukovskaya, L., Mizerev, A., Fedorov, Yu., Bobylyova, A., Maksimov, A., Moiseeva, A., Anisimov, A., and Jonusauskas, G., J. Phys. Org. Chem., 2010, vol. 23, p. 246.Google Scholar
  7. 7.
    Selector, S., Fedorova, O., Lukovskaya, E., Anisimov, A., Fedorov, Yu., Tarasova, N., Raitman, O., Fages, F., and Arslanov, V., J. Phys. Chem. B, 2012, vol. 116, p. 1482.CrossRefGoogle Scholar
  8. 8.
    Bradshaw, J.S. and Izatt, R.M., Acc. Chem. Res., 1997, vol. 30, p. 338.CrossRefGoogle Scholar
  9. 9.
    Vedernikov, A.I., Lobova, N.A., Ushakov, E.N., Alfimov, M.V., and Gromov, S.P., Mendeleev Commun., 2005, vol. 15, p. 173.CrossRefGoogle Scholar
  10. 10.
    Lukovskaya, E., Bobylyova, A., Fedorov, Yu., Maksimov, A., Anisimov, A., Fedorova, O., Jonusauskas, G., and Fages, F., Chem. Phys. Chem., 2010, vol. 11, p. 3152.CrossRefGoogle Scholar
  11. 11.
    Wei, Y., Yang, Y., and Yeh, J.M., Chem. Mater., 1996, vol. 8, p. 2659.CrossRefGoogle Scholar
  12. 12.
    Gans, P., Sabbatini, A., and Vacca, A., Talanta, 1996, vol. 43, p. 1739.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • E. V. Lukovskaya
    • 1
    Email author
  • A. A. Kosmacheva
    • 1
  • O. A. Fedorova
    • 1
    • 2
  • A. A. Bobyleva
    • 1
  • A. V. Dolganov
    • 2
  • N. E. Shepel’
    • 2
  • Yu. V. Fedorov
    • 1
    • 2
  • V. V. Novikov
    • 2
  • A. V. Anisimov
    • 1
  1. 1.Faculty of ChemistryMoscow State UniversityMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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