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Oxidation of polyfunctional sulfides with chlorine dioxide

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Abstract

3-Benzylsulfanyl-4,5-diphenyl-4H-1,2,4-triazole, 5-methylsulfanyl-1-phenyl-1H-tetrazole, 2-methylsulfanyl-1H-benzimidazole, 2-benzylsulfanyl-1H-benzimidazole, and 1-butylsulfanyl-4-nitrobenzene were oxidized to the corresponding sulfoxides with chlorine dioxide using different modes of oxidant supply. The oxidation process was characterized by high chemoselectivity.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Research Center, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167982, Russia

    I. V. Loginova, K. S. Rodygin, S. A. Rubtsova & A. V. Kuchin

  2. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    P. A. Slepukhin

  3. Vekton Closed Corporation, St. Petersburg, Russia

    V. A. Polukeev

Authors
  1. I. V. Loginova
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  2. K. S. Rodygin
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  3. S. A. Rubtsova
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  4. P. A. Slepukhin
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  5. A. V. Kuchin
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  6. V. A. Polukeev
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Corresponding author

Correspondence to I. V. Loginova.

Additional information

Original Russian Text © I.V. Loginova, K.S. Rodygin, S.A. Rubtsova, P.A. Slepukhin, A.V. Kuchin, V.A. Polukeev, 2011, published in Zhurnal Organicheskoi Khimii, 2011, Vol. 47, No. 1, pp. 125–130.

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Loginova, I.V., Rodygin, K.S., Rubtsova, S.A. et al. Oxidation of polyfunctional sulfides with chlorine dioxide. Russ J Org Chem 47, 124–130 (2011). https://doi.org/10.1134/S1070428011010167

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  • DOI: https://doi.org/10.1134/S1070428011010167

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