Russian Journal of Organic Chemistry

, Volume 47, Issue 1, pp 66–73 | Cite as

Dipolar cycloaddition of N-aryl-C-(2,2-dichloro-1-phenylcyclopropyl)nitrones to N-arylmaleimides

  • A. P. Molchanov
  • P. S. Sorokoumov
  • J. Kopf
  • R. R. Kostikov


1,3-Dipolar cycloaddition of N-aryl-C-(2,2-dichloro-1-phenylcyclopropyl)nitrones to N-arylmaleimides stereoselectively gives substituted pyrrolo[3,4-d]isoxazolidines as mixtures of two diastereoisomers differing by configuration at the C1′ atom of the cyclopropane ring in the substituent on C3. Substituents in the aromatic rings of the initial nitrone and maleimide do not affect the stereochemistry of the process.


Dione Cyclopropyl Cyclopropane Ring Dipolar Cycloaddition Isoxazolidine 
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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • A. P. Molchanov
    • 1
  • P. S. Sorokoumov
    • 1
  • J. Kopf
    • 2
  • R. R. Kostikov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Institut für Anorganische ChemieHamburgGermany

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