Russian Journal of Organic Chemistry

, Volume 46, Issue 12, pp 1786–1789 | Cite as

Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol

  • O. V. Ardashov
  • A. M. Genaev
  • I. V. Il’ina
  • D. V. Korchagina
  • K. P. Volcho
  • N. F. Salakhutdinov


Hydrogenation of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol was studied. Nickel chloride-sodium tetrahydridoborate system turned out to selectively reduce the double bond in the isopropenyl group. The results of conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol and its partly and completely hydrogenated derivatives were in a good agreement with the NMR data.


Diol Potential Energy Surface Conformational Analysis Isopropyl Group Raney Nickel 
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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • O. V. Ardashov
    • 1
  • A. M. Genaev
    • 1
  • I. V. Il’ina
    • 1
  • D. V. Korchagina
    • 1
  • K. P. Volcho
    • 1
  • N. F. Salakhutdinov
    • 1
  1. 1.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

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