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Russian Journal of Organic Chemistry

, Volume 46, Issue 9, pp 1269–1276 | Cite as

The comparison of addition of molecules possessing P(V)-H bond to alkynes catalyzed with Pd and Ni complexes

  • V. P. AnanikovEmail author
  • L. L. Khemchyan
  • I. P. Beletskaya
Article

Abstract

Main factors have been analyzed necessary for creation of an efficient catalytic system for alkynes hydrophosphorylation based on nickel complexes, and a valid model system was suggested for the comparison with palladium complexes. It has been discovered for the first time that the insertion of an alkyne into the metal-hydrogen bond occurs with a considerably lower activation barrier than into the metal-phosphorus bond, whereas the variation in the reaction energy corresponds in both cases to an exothermic reaction. Under the optimized conditions the transformation catalyzed by nickel complexes does not require acid addition and may proceed even in the absence of a phosphine ligand.

Keywords

Alkyne Acac Nickel Complex Phosphine Ligand Terminal Alkyne 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • V. P. Ananikov
    • 1
    Email author
  • L. L. Khemchyan
    • 1
  • I. P. Beletskaya
    • 2
  1. 1.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Lomonosov Moscow State UniversityMoscowRussia

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