Russian Journal of Applied Chemistry

, Volume 91, Issue 11, pp 1821–1829 | Cite as

Influence of Synthesis Conditions on Properties of MWW Zeolites

  • E. E. KnyazevaEmail author
  • I. V. Dobryakova
  • A. V. Shkuropatov
  • O. A. Ponomareva
  • Yu. G. Kolyagin
  • I. I. Ivanova
Technological Production of New Materials


The influence of the preparation conditions on the physicochemical properties of zeolite MWW at varying the type of source of SiO2, the concentration parameters of the reaction mixture, temperature and duration of crystallization. The synthesis conditions providing a high degree of utilization of inorganic sources of raw materials and an MWW zeolite yield of 96% were determined. It was shown that performing the crystallization at 150°C results in that uniform-size crystals of MWW zeolite are formed. The concentrating limits of the reaction mixture were determined, at which a pure-phase MWW zeolite with pore volume of 0.33–0.34 cm3 g–1 and micropore volume of 0.17–0.18 cm3 g–1 can be obtained.


MWW zeolite synthesis conditions crystallization product 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Degnan, T.F., Smith, C.M., and Venkat, C.R., Appl. Catal. A, 2001, vol. 221, nos. 1–2, pp. 283–294.CrossRefGoogle Scholar
  2. 2.
    Díaz, U. and Corma, A., Dalton Trans., 2014, vol. 43, pp. 10292–10316.CrossRefGoogle Scholar
  3. 3.
    Kumar, Sh., Pusparatu, S., Komura, K., Kubota, Y., and Sugi, Y., Mater. Trans., Spec. Issue, 2005, vol. 46, no. 12, pp. 2651–2658.CrossRefGoogle Scholar
  4. 4.
    Liu, Z., Shen, S., Tian, B., Sun, J., Tu, B., and Zhao, D., Chin. Sci. Bull., 2004, vol. 49, no. 6, pp. 556–561.CrossRefGoogle Scholar
  5. 5.
    Wu, Y., Ren, X., Lu, Y., and Wang, J., Microporous Mesoporous Mater., 2008, vol. 112, nos. 1–3, pp. 138–146.CrossRefGoogle Scholar
  6. 6.
    Leonowicz, M.E., Lawton, J.A., Lawton, S.L., and Rubin, M.K., Science, 1994, vol. 264, pp. 1910–1913.CrossRefGoogle Scholar
  7. 7.
    Juttu, G.G. and Lobo, R.F., Microporous Mesoporous Mater., 2000, vol. 40, no. 1, pp. 9–23.CrossRefGoogle Scholar
  8. 8.
    Li, Y., Guo, W., Fan, W., and Yuan, S., J. Mol. Catal. A: Chem., 2011, vol. 338, nos. 1–2, pp. 24–32.Google Scholar
  9. 9.
    Corma, A., Fornes, V., Pergher, S.B., Maesen, Th.L.M., and Buglass, J.G., Nature, 1998, vol. 396, no. 26, pp. 353–356.CrossRefGoogle Scholar
  10. 10.
    Corma, A., Fornés, V., Guil, J.M., Pergher, S., Maesen, Th.L.M., and Buglass, J.G., Microporous Mesoporous Mater., 2000, vol. 38, no. 23, pp. 301–309.CrossRefGoogle Scholar
  11. 11.
    Wu, P., Ruan, J., Wang, L., Wu, L., Wang, Y., Liu, Y., Fan, W., He, M., Terasaki, O., and Tatsumi, T.J., Am. Chem. Soc., 2008, vol. 130, pp. 8178–8187.CrossRefGoogle Scholar
  12. 12.
    Song, K., Guan, J., Wu, S., Yang, Y., Liu, B., and Kan, Q., Catal. Lett., 2008, vol. 126, nos. 3–4, pp. 333–340.CrossRefGoogle Scholar
  13. 13.
    Diáz, U., Fornes, V., and Corma, A., Microporous Mesoporous Mater., 2006, vol. 90, nos. 1–3, pp. 73–80.CrossRefGoogle Scholar
  14. 14.
    Corma, A., Corell, C., and Pérez-Pariente, J., Zeolites, 1995, vol. 15, no. 1, pp. 2–8.CrossRefGoogle Scholar
  15. 15.
    Cheng, M., Tan, D., Liu, X., and Han, X., Microporous Mesoporous Mater., 2001, vol. 42, nos. 2–3, pp. 307–316.CrossRefGoogle Scholar
  16. 16.
    Güray, I., Warzywoda, J., Bac, N., and Sacco, A., Microporous Mesoporous Mater., 1999, vol. 31, no. 3, pp. 241–251.CrossRefGoogle Scholar
  17. 17.
    Schwanke, A.J., Pergher, S., Díaz, U., and Corma, A., Microporous Mesoporous Mater., 2017, vol. 254, no. 1, pp. 17–27.CrossRefGoogle Scholar
  18. 18.
    Wang, Y., Gao, Y., Xie, S., Liu, Sh., Chen, F., Xin, W., Zhu, X., Li, X., Jiang, N., and Xu, L., Catal. Today, 2018, vol. 316, pp. 71–77.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. E. Knyazeva
    • 1
    • 2
    Email author
  • I. V. Dobryakova
    • 1
  • A. V. Shkuropatov
    • 1
  • O. A. Ponomareva
    • 1
    • 2
  • Yu. G. Kolyagin
    • 1
  • I. I. Ivanova
    • 1
    • 2
  1. 1.Lomonosov Moscow State UniversityMoscowRussia
  2. 2.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia

Personalised recommendations