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Russian Journal of Applied Chemistry

, Volume 91, Issue 11, pp 1742–1749 | Cite as

Synthesis and Properties of Poly(Propylene Glycol Maleate Phthalate)–Styrene Copolymers as a Base of Composite Materials

  • M. Zh. Burkeyev
  • A. K. KovalevaEmail author
  • J. Plocek
  • E. M. Tazhbayev
  • G. K. Burkeyeva
  • A. N. Bolatbai
  • S. Zh. Davrenbekov
Macromolecular Compounds and Polymeric Materials
  • 5 Downloads

Abstract

Comparative analysis of the physicochemical properties of styrene solutions of poly(propylene glycol maleate phthalate) with different initial reactant ratio was performed. Increased content of phthalic anhydride in the initial monomer mixture in the synthesis of the unsaturated polyester leads to worse properties of the ready product, poly(propylene glycol maleate phthalate)–styrene copolymer prepared by cold curing. Solutions of poly(propylene glycol maleate phthalate) in styrene with ~30 wt % styrene content exhibit the highest viscosity, allowing the use of the cured product as a structural composite material. The solutions containing ~40 wt % styrene have lower viscosity and are suitable for preparing less hard plastics for general purposes.

Keywords

poly(propylene glycol maleate phthalate) styrene unsaturated polyester curing structural materials 

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References

  1. 1.
    Dholakiya, B.Z., Unsaturated Polyester Resin for Specialty Application, Ch. 8 of Polyester, Saleh, H.E.-D.M., InTech, 2012. 202 p.Google Scholar
  2. 2.
    Sanchez, E.M.S., Zavaglia, C.A.C., and Felisberti, M.I., Polymer, 2000, vol. 41, pp. 765–769.CrossRefGoogle Scholar
  3. 3.
    Sadler, J.M., Toulan, F.R., Palmese, G.R., and La Scala, J.J., J. Appl. Polym. Sci., 2015, vol. 132, pp. 1–11.CrossRefGoogle Scholar
  4. 4.
    Dholakiya, B.Z. and Patel, K.D., MMAIJ, 2007, vol. 3, no. 4, pp. 169–175.Google Scholar
  5. 5.
    Gonsalves, F.A.M.M., Fonseca, A.C., Domingos, M., Gloria, A., Serra, A.C., and Coelho, J.F.J., Prog. Polym. Sci., 2016, vol. 68, pp. 1–34.CrossRefGoogle Scholar
  6. 6.
    Rusmirovic, J.D., Trifkovic, K.T., Bugarski, B., Pavlovic, V.B., Dzunuzovic, J., Tomic, M., and Marinkovic, A.D., Express Polym. Lett., 2016, vol. 10, pp. 139–159.CrossRefGoogle Scholar
  7. 7.
    Sunemi, H.T., Fushiki, Y., Nishimura, A., and Kawai, Y., Prepolymer Polyester Resin Compositions and Electrical Laminates Made Therefrom, CA 1337915, Kanegafuchi Chemical Ind., 1996.Google Scholar
  8. 8.
    Boenig, H.V., Unsaturated Polyesters: Structure and Properties, Amsterdam: Elsevier, 1964.Google Scholar
  9. 9.
    Fonseca, A.C., Costa, C.S.M.F., Marques, Y.M.P., Coelho, J.F.J., and Serra, A.C., J. Mater. Sci., 2017, vol. 52, no. 3, pp. 1272–1284.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. Zh. Burkeyev
    • 1
  • A. K. Kovaleva
    • 1
    Email author
  • J. Plocek
    • 2
  • E. M. Tazhbayev
    • 1
  • G. K. Burkeyeva
    • 1
  • A. N. Bolatbai
    • 1
  • S. Zh. Davrenbekov
    • 1
  1. 1.Buketov State UniversityKaragandaKazakhstan
  2. 2.Institute of Inorganic ChemistryCzech Academy of SciencesRez, Husinec-RezCzech Republic

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