Russian Journal of Applied Chemistry

, Volume 88, Issue 8, pp 1255–1260 | Cite as

Effect of the nature of a solvent on properties of Pd–P catalysts in hydrogenation of ortho-chloronitrobenzene

  • N. I. Skripov
  • L. B. Belykh
  • T. P. Sterenchuk
  • F. K. Schmidt


Fundamental aspects of the influence of solvent nature on the activity and selectivity of palladium catalysts modified with white phosphorus in hydrogenation of ortho-chloronitrobenzene were determined. The conditions are suggested in which the chemoselectivity of palladium catalysts modified with white phosphorus can be raised to 93–95% with respect to ortho-chloroaniline in the temperature range 30–80°C without accumulation in the reaction system of undesirable products, ortho-chlorophenylhydroxylamine and azo- and azoxychlorobenzene.


Aniline Acac Palladium Catalyst Vanadium Compound Chloroaniline 
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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • N. I. Skripov
    • 1
  • L. B. Belykh
    • 1
  • T. P. Sterenchuk
    • 1
  • F. K. Schmidt
    • 1
  1. 1.Irkutsk State UniversityIrkutskRussia

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