Advertisement

Russian Journal of Applied Chemistry

, Volume 88, Issue 8, pp 1255–1260 | Cite as

Effect of the nature of a solvent on properties of Pd–P catalysts in hydrogenation of ortho-chloronitrobenzene

  • N. I. Skripov
  • L. B. Belykh
  • T. P. Sterenchuk
  • F. K. Schmidt
Catalysis

Abstract

Fundamental aspects of the influence of solvent nature on the activity and selectivity of palladium catalysts modified with white phosphorus in hydrogenation of ortho-chloronitrobenzene were determined. The conditions are suggested in which the chemoselectivity of palladium catalysts modified with white phosphorus can be raised to 93–95% with respect to ortho-chloroaniline in the temperature range 30–80°C without accumulation in the reaction system of undesirable products, ortho-chlorophenylhydroxylamine and azo- and azoxychlorobenzene.

Keywords

Aniline Acac Palladium Catalyst Vanadium Compound Chloroaniline 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Colguhoun, H.M., Holton, J., Thompson, D.J., et al., New Pathways for Organic Synthesis, New York: Plenum, 1984.CrossRefGoogle Scholar
  2. 2.
    Widegren, J.A. and Finke, R.G., J. Mol. Catal. A: Chem., 2003, vol. 191, pp. 187–207.CrossRefGoogle Scholar
  3. 3.
    Coq, B. and Figueras, F., Coord. Chem. Rev., 1998, vols. 178–180, pp. 1753–1783.CrossRefGoogle Scholar
  4. 4.
    Wang, X., Liang, M., Zhang, J., et al., Current Org. Chem., 2007, vol. 11, pp. 299–314.CrossRefGoogle Scholar
  5. 5.
    Ramos, A., Schmal, M., Aranda, D., et al., J. Catal., 2000, vol. 192, pp. 423–431.CrossRefGoogle Scholar
  6. 6.
    Oyama, S.T., Gott, T., Zhao, H., et al., Catal. Today, 2009, vol. 143, pp. 94–107.CrossRefGoogle Scholar
  7. 7.
    Blaser, H.U., Science, 2006, vol. 313, pp. 312–313.CrossRefGoogle Scholar
  8. 8.
    Gorbunov, V.V. and Shidlovskii, A.A., Fiz. Goreniya Vzryva, 1970, no. 4, p.471.Google Scholar
  9. 9.
    EP Patent 0,842,920 B1 (publ. 2004).Google Scholar
  10. 10.
    Simagina, V.I., Netskina, V.I., Tayban, E.S., et al., Appl. Catal. A, 2010, vol. 379, pp. 87–94.CrossRefGoogle Scholar
  11. 11.
    Corma, A., Serna, P., Concepcion, P., et al., J. Am. Chem. Soc., 2008, vol. 130, pp. 8748–8753.CrossRefGoogle Scholar
  12. 12.
    Cecilia, J.A., Jimenez-Moralesa, I., Infantes-Molin, A., et al., J. Mol. Catal. A: Chem., 2013, vols. 368–369, pp. 78–87.CrossRefGoogle Scholar
  13. 13.
    Yang, P., Jiang, Z., Ying, P., et al., J. Catal., 2008, vol. 253, pp. 66–73.CrossRefGoogle Scholar
  14. 14.
    Ni, Y., Li, J., Zhang, L., et al., Mater. Res. Bull., 2009, vol. 44, pp. 1166–1172.CrossRefGoogle Scholar
  15. 15.
    Yang, S. and Prins, R., Chem. Comm., 2005, pp. 4178–4180.Google Scholar
  16. 16.
    Belykh, L.B., Skripov, N.I., Schmidt, F.K., et al., Kinet. Catal., 2010, vol. 51, no. 1, pp. 42–49.CrossRefGoogle Scholar
  17. 17.
    Belykh, L.B., Skripov, N.I., Stepanova, T.P., et al., Current Nanosci., 2015, vol. 11, no. 2, pp. 175–185.CrossRefGoogle Scholar
  18. 18.
    Belykh, L.B., Skripov, N.I., Schmidt, F.K., et al., Kinet. Catal., 2015, vol. 56, no. 2, pp. 181–189.CrossRefGoogle Scholar
  19. 19.
    Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley & Sons, 1972.Google Scholar
  20. 20.
    US Patent 3474464 (publ. 1969).Google Scholar
  21. 21.
    Lefedova, O.V., Ulitin, M.V., and Barbov, A.V., Ros. Khim. Zh., 2006, vol. 1, no. 3, pp. 123–131.Google Scholar
  22. 22.
    Kratky, V., Kralik, M., Kaszonyi, A., et al., Collect. Czech. Chem. Commun., 2003, vol. 68, pp. 1819–1832.CrossRefGoogle Scholar
  23. 23.
    Brunner, E., J. Chem. Eng., 1985, vol. 30, pp. 269–273.Google Scholar
  24. 24.
    Pandarus, V., Ciriminna, R., Beland, F., et al., Adv. Synth. Catal., 2011, vol. 353, pp. 1306–1316.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • N. I. Skripov
    • 1
  • L. B. Belykh
    • 1
  • T. P. Sterenchuk
    • 1
  • F. K. Schmidt
    • 1
  1. 1.Irkutsk State UniversityIrkutskRussia

Personalised recommendations