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Russian Journal of Applied Chemistry

, Volume 88, Issue 2, pp 226–231 | Cite as

Decomposition of cobalt(III) nitrotetrazolato amminates under the action of laser light

  • A. S. Tverjanovich
  • A. O. Aver’yanov
  • M. A. Ilyshin
  • Yu. S. Tverjanovich
  • A. V. Smirnov
Inorganic Synthesis and Industrial Inorganic Chemistry

Abstract

IR spectroscopy was used to study (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (1) and {bis-[cis-(5-nitrotetrazolato-N2)]}tetraaminecobalt(III) perchlorate (2) and products of their decomposition under the action of laser light resonant in energy with d-d transitions observed in these complexes. The electronic spectra of complexes 1 and 2 are governed by d-d transitions of cobalt ions (1A1g1T2g at 328–330 nm and 1A1g1T1g at 455–466 nm) and ligand-metal charge transfer in a shorter wavelength range. Comparison of the vibration spectra of the decomposition products and starting complexes suggests that cobalt amminates decompose to give additional [−NO2] groups in unknown compounds.

Keywords

Perchlorate Laser Light Onset Point Short Wavelength Range Cobalt Salt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Moore, D.S., Rev. Sci. Instrum., 2004, vol. 75, pp. 2499–2512.CrossRefGoogle Scholar
  2. 2.
    De Lucia, F.C., Gottfried, J.L., and Miziolek, A.W., Opt. Express, 2009, vol. 17, no. 2, pp. 419–425.CrossRefGoogle Scholar
  3. 3.
    Wynn, C.M., Palmacci, S., Kunz, R.R., and Rothshild, M., Lincoln Lab. J., 2010, vol. 18, no. 6, pp. 5399–5406.Google Scholar
  4. 4.
    Chen, L., Sheng, D., Ma, F., et al., Chin. J. Ener g. Mater., 2007, vol. 15, no. 3, pp. 217–219.Google Scholar
  5. 5.
    Zhilin, A.Yu., Ilyushin, M.A., Tselinskii, I.V., et al., Russ. J. Appl. Chem., 2003, vol. 76, no. 4, pp. 572–576.CrossRefGoogle Scholar
  6. 6.
    Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984, 2nd ed.Google Scholar
  7. 7.
    Bunel, S. and Ibarra, C., Polyhedron, 1985, vol. 4, no. 9, pp. 1537–1542.CrossRefGoogle Scholar
  8. 8.
    Mikulia, E., Migdal-Mikulia, A., Gorskaa, N., et al., J. Mol. Struct., 2003, pp. 519–524.Google Scholar
  9. 9.
    Kloprogge, J.T., Wharton, D., Hickey, L., and Frost, R.L., Am. Mineral., 2002, vol. 87, nos. 5–6, pp. 623–629.Google Scholar
  10. 10.
    Terrasse, J.M., Poulet, H., and Mathieu, J.P., Spectrochim. Acta, 1964, vol. 20, pp. 305–315.CrossRefGoogle Scholar
  11. 11.
    Block, H., Trans. Faraday Soc., 1959, vol. 55, pp. 867–875.CrossRefGoogle Scholar
  12. 12.
    Talawar, M.B., Agrawal, A.P., and Asthana, S.N., J. Hazard. Mater., 2005, vol. 120, nos. 1–3, pp. 25–35.CrossRefGoogle Scholar
  13. 13.
    Thomas, S., Biswas, N., Venkateswaran, S., et al., J. Phys. Chem. A, 2005, vol. 109, pp. 9928–9934.CrossRefGoogle Scholar
  14. 14.
    Billesa, F., Endredia, H., and Kereszturyb, G., J. Mol. Struct.: THEOCHEM, 2000, vol. 530, pp. 183–200.CrossRefGoogle Scholar
  15. 15.
    Bugalho, S.C.S., Macoas, E.M.S., Cristiano, M.L.S., and Fausto, R., Phys. Chem. Chem. Phys., 2001, vol. 3, pp. 3541–3547.CrossRefGoogle Scholar
  16. 16.
    Larkin, P., Infrared and Raman Spectroscopy; Principles and Spectral Interpretation, Burlington: Elsevier Sci., 2011.Google Scholar
  17. 17.
    Kazuo Nakamoto, Junnosuke Fujita, and Hiromu Murata, J. Am. Chem. Soc., 1958, vol. 80, no. 18, pp. 4817–4823.CrossRefGoogle Scholar
  18. 18.
    Brown, M.E., Dollimore, D., and Galwey, A.K., Comprehensive Chemical Kinetics, vol. 22, Reactions in the Solid State, Amsterdam; Oxford; New York: Elsevier, 1980.Google Scholar
  19. 19.
    Marletta, M.A. and Stuehr, D.J., Proc. Third Int. Conf. on Superoxide and Superoxide Dismutase, Cohen, G. and Greenwald, R.A., Eds., New York; Amsterdam; Oxford: Elsevier Biomed., 1982, pp. 56–61.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. S. Tverjanovich
    • 1
  • A. O. Aver’yanov
    • 1
  • M. A. Ilyshin
    • 2
  • Yu. S. Tverjanovich
    • 1
  • A. V. Smirnov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.St. Petersburg State Technological Institute (Technical University)St. PetersburgRussia

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