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Russian Journal of Applied Chemistry

, Volume 88, Issue 2, pp 197–207 | Cite as

Effect of kinetic features in synthesis of hybrid copolymers based on Ti(OPri)4 and hydroxyethyl methacrylate on their structure and properties

  • E. V. Salomatina
  • A. N. Moskvichev
  • A. V. Knyazev
  • L. A. Smirnova
Inorganic Synthesis and Industrial Inorganic Chemistry

Abstract

Effect of synthesis conditions on the structure and optical properties of hybrid copolymers based on Ti(OPri)4 and hydroxyethyl methacrylate was determined. Raising the concentration of the methacrylic monomer in the system leads to a longer hydrolytic polycondensation of titanium alkoxide and faster radical polymerization of the organic monomer. Copolymers containing poly(titanium oxide) with a nearly anatase structure were obtained in the conditions of a double-stage synthesis including successive stages of low-temperature hydrolytic polycondensation and polymerization. In the case of a single-stage synthesis at 70°C, which combines simultaneously occurring polycondensation and polymerization processes, the copolymer contains the anatase (75%) and rutile (25%) forms of poly(titanium oxide).

Keywords

Radical Polymerization Polycondensation HEMA Vinyl Monomer Ethyl Methacrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • E. V. Salomatina
    • 1
  • A. N. Moskvichev
    • 2
  • A. V. Knyazev
    • 1
  • L. A. Smirnova
    • 1
  1. 1.Lobachevsky State University of Nizhni NovgorodNizhni NovgorodRussia
  2. 2.Institute for Problems of Machine BuildingRussian Academy of SciencesNizhni NovgorodRussia

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