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Russian Journal of Applied Chemistry

, Volume 84, Issue 3, pp 400–406 | Cite as

Thermodynamic and kinetic aspects of a single-reactor synthesis of 5-amino-3-methyl-1,2,4-triazole hydrochloride from aminoguanidine and acetic acid

  • E. V. Tarasova
  • V. M. Chernyshev
  • A. V. Chernysheva
  • R. S. Abagyan
Organic Synthesis and Industrial Organic Chemistry

Abstract

Fundamental thermodynamic and kinetic aspects of the reaction in which acetic acid guanyl hydrazide is formed from aminoguanidine and acetic acid in aqueous solutions at pH 0.6-1.5 and the kinetics of cyclization of acetic acid guanyl hydrazide hydrochloride to 5-amino-3-methyl-1,2,4-triazole hydrochloride in a melt were studied. Methods for synthesis of acetic acid guanyl hydrazide hydrochlorides and 5-amino-3-methyl-1,2,4-triazole hydrochloride were developed.

Keywords

Triazole Hydrazide AcOH Malonic Acid Aminoguanidine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • E. V. Tarasova
    • 1
  • V. M. Chernyshev
    • 1
  • A. V. Chernysheva
    • 1
  • R. S. Abagyan
    • 1
  1. 1.South-Russian State Technical University (Novocherkassk Polytechnic Institute)Novocherkassk, Rostov-on-Don oblastRussia

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