Russian Journal of Applied Chemistry

, Volume 82, Issue 6, pp 935–939 | Cite as

Synthesis and study of solid solutions between cobalt and nickel phosphates with varied degree of anion protonation

  • V. N. Viter
  • P. G. Nagornyi
Inorganic Synthesis and Industrial Inorganic Chemistry

Abstract

Continuous substitutional solid solutions between cobalt and nickel phosphates with varied degree of anion protonation were obtained: Co1−xNixHPO4·1.5H2O and (Co1−xNix)3(PO4)2·8H2O, where 0 ≤ x ≤ 1.00. The thermolysis of the solid solutions was studied by the example of Co1−xNixHPO4·1.5H2O. The phases synthesized were compared with the previously described continuous solid solution Co1−xNix(H2PO4)2·2H2O.

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References

  1. 1.
    Gao, D. and Gao, Q., Microp. Mesop. Mater., 2005, vol. 85, no. 3, p. 365.CrossRefGoogle Scholar
  2. 2.
    Ghorai, T.K., Dhak, D., Azizan, A., and Pramanik, P., Mater. Sci. Eng., Ser. B, 2005, vol. 121, no. 3, p. 216.CrossRefGoogle Scholar
  3. 3.
    Legrouri, A., Lenzi, J., and Lenzi, M., Mater. Chem. Phys., 1994, vol. 38, no. 1, p. 94.CrossRefGoogle Scholar
  4. 4.
    Legrouri, A., Lenzi, J., and Lenzi, M., React. Kinet. Catal. Lett., 1992, vol. 48, no. 2, p. 349.CrossRefGoogle Scholar
  5. 5.
    Aaddane, A., Kacimi, M., and Ziyad, M., Catal. Lett., 2001, vol. 73, no. 1, p. 47.CrossRefGoogle Scholar
  6. 6.
    Abu, I.I. and Smith, K.J., Appl. Catal. A: General, 2007, vol. 328, no. 1, p. 58.CrossRefGoogle Scholar
  7. 7.
    Song, L., Li, W., Wang, G., et al., Catal. Today, 2007, vol. 125, nos. 3–4, p. 137.CrossRefGoogle Scholar
  8. 8.
    Nagai, M., Fukiage, T., and Kurata, Sh., Catal. Today, 2005, vol. 106, nos. 1–4, p. 201.CrossRefGoogle Scholar
  9. 9.
    Sun, F., Wu, W., Wu, Z., et al., J. Catal., 2004, vol. 228, no. 2, p. 298.CrossRefGoogle Scholar
  10. 10.
    Korsunskii, L.F., Kalinskaya, T.V., and Stepin, S.N., Neorganicheskie pigmenty (Inorganic Pigments), St. Petersburg: Khimiya, 1992.Google Scholar
  11. 11.
    JCPDS, Int. Center for Diffraction Data, nos. 39–698, 39–705, 39–706, 33–432, 33–951.Google Scholar
  12. 12.
    Viter, V.N. and Nagornyi, P.G., Zh. Neorg. Khim., 2007, vol. 52, no. 1, p. 19.Google Scholar
  13. 13.
    Konstant, Z.A. and Dindune, A.P., Fosfaty dvukhvalentnykh metallov (Phosphates of Bivalent Metals), Riga: Zinatne, 1987.Google Scholar
  14. 14.
    Pyatnitskii, I.V., Analiticheskaya khimiya kobal’ta (Analytical Chemistry of Cobalt), Moscow: Nauka, 1965.Google Scholar
  15. 15.
    Zhivopistsev, V.P. and Selezneva, E.A., Analiticheskaya khimiya tsinka (Analytical Chemistry of Zinc), Moscow: Nauka, 1975.Google Scholar
  16. 16.
    Qualitative Inorganic Analysis, Charlot, G., Ed., Thomas Press, 2007.Google Scholar
  17. 17.
    GOST (State Standard) 20851-75: Mineral Fertilizers: Methods for Analysis, Moscow: Izd. Standartov, 1986.Google Scholar
  18. 18.
    Pechkovskii, V.V., Mel’nikova, R.Ya., Dzyuba, E.D., et al., Atlas infrakrasnykh spektrov fosfatov: Ortofosfaty (Atlas of IR Spectra of Phosphates), Moscow: Nauka, 1981.Google Scholar
  19. 19.
    The Microscopical Characters of Artificial Inorganic Solid Substances: Optical Properties of Artificial Minerals, Winchell, A.N., and Winchell, H., Eds., Academic Press, 1964.Google Scholar
  20. 20.
    Nord, A.G., Acta Chem. Scand., 1982, vol. A36, no. 2, p. 95.CrossRefGoogle Scholar
  21. 21.
    Nord, A.G., Mater. Res. Bull., 1981, vol. 16, p. 1121.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • V. N. Viter
    • 1
  • P. G. Nagornyi
    • 1
  1. 1.Shevchenko National UniversityKievUkraine

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