Russian Journal of Applied Chemistry

, Volume 81, Issue 11, pp 2002–2007 | Cite as

Effect of Cr(III), Fe(III), Co(III), and Ni(II) acetylacetonates on the formation and thermal oxidative degradation of epoxy-anhydride polymers and composites

  • A. A. Lugovaya
  • V. M. Mikhal’chuk
  • V. A. Beloshenko
  • D. V. Gurtovoi
Macromolecular Compounds and Polymeric Materials

Abstract

The effect of Cr(III), Fe(III), Co(III), and Ni(II) acetylacetonates on epoxy-anhydride polycondensation in preparation of unmodified polymeric materials based on UP-650T epoxy resin and isomethyltetrahydrophthalic anhydride and of epoxy-siloxane hybrid composites was examined The resistance of the materials obtained to high-temperature oxidation and thermal oxidative degradation was evaluated.

Keywords

Acac Acetylacetonates Hybrid Composite Epoxy Polymer Cationic Polymerization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Zaitsev, Yu.S., Kochergin, Yu.S., Pakter, M.K., and Kucher, R.V., Epoksidnye oligomery i kleevye kompozitsii (Epoxy Oligomers and Adhesive Compounds), Kiev: Naukova Dumka, 1990.Google Scholar
  2. 2.
    Matejka, L., Plestil, J., and Dusek, K., J. Non-Cryst. Solids, 1998, vol. 226, pp. 114–121.CrossRefGoogle Scholar
  3. 3.
    Matejka, L., Dukh, O., and Kolařik, J., Polymer, 2000, vol. 41, pp. 1449–1459.CrossRefGoogle Scholar
  4. 4.
    Perminov, V.P., Modyanova, A.G., Ryabkov, Yu.I., et al., Zh. Prikl. Khim., 2002, vol. 75, no. 4, pp. 650–654.Google Scholar
  5. 5.
    Mascia, L. and Tang, T., J. Sol-Gel Sci. Technol., 1998, vol. 13, pp. 405–408.CrossRefGoogle Scholar
  6. 6.
    Karkozov, V.G., Rodchenko, M.B., Nikolaev, A.F., and Emel’yanova, E.I., Plast. Massy, 1989, no. 1, pp. 28–29.Google Scholar
  7. 7.
    Nikolaev, A.F., Rodchenko, M.B., Karkozov, V.G., et al., Plast. Massy, 1989, no. 4, pp. 933–937.Google Scholar
  8. 8.
    Smith, J.D.B., J. Appl. Polym. Sci., 1981, vol. 26, pp. 979–986.CrossRefGoogle Scholar
  9. 9.
    Karkozov, V.G., Rodchenko, M.B., and Nikolaev, A.F., Plast. Massy, 1989, no. 1, pp. 201–203.Google Scholar
  10. 10.
    Mikhal’chuk, V.M., Kryuk, T.V., and Nikolaevskii, A.N., Zh. Prikl. Khim., 1996, vol. 69, no. 6, pp. 1008–1013.Google Scholar
  11. 11.
    Mikhal’chuk, V.M., Kryuk, T.V., and Nikolaevskii, A.N., Zh. Prikl. Khim., 1996, vol. 69, no. 8, pp. 1354–1358.Google Scholar
  12. 12.
    Kryuk, T.V., Mikhal’chuk, V.M., Volnyanskaya, R.I., and Nikolaevskii, A.N., Vopr. Khim. Khim. Tekhnol., 2002, no. 3, pp. 73–76.Google Scholar
  13. 13.
    Kryuk, T.V., Mikhal’chuk, V.M., Volnyanskaya, R.I., and Nikolaevskii, A.N., Ukr. Khim. Zh., 2002, vol. 68, no. 5, pp. 58–62.Google Scholar
  14. 14.
    Kryuk, T.V., Mikhal’chuk, V.M., Nikolaevskii, A.N., et al., Plast. Massy, 2001, no. 3, pp. 12–14.Google Scholar
  15. 15.
    Bershtein, V.A. and Egorov, V.M., Differentsial’naya skaniruyushchaya kalorimetriya v fizikokhimii polimerov (Differential Scanning Calorimetry in Polymer Physics and Chemistry), Leningrad: Khimiya, 1990.Google Scholar
  16. 16.
    Elegant, L., Tomi, P., Augier, G., et al., J. Therm. Anal., 1986, vol. 31, pp. 1351–1358.CrossRefGoogle Scholar
  17. 17.
    Zhil’tsova, S.V., Mikhal’chuk, V.M., Petrova, E.M., et al., Zh. Prikl. Khim., 2007, vol. 80, no. 3, pp. 479–483.Google Scholar
  18. 18.
    Savenkova, L.A., Mikhal’chuk, V.M., Rybachenko, V.I., et al., Vopr. Khim. Khim. Tekhnol., 2007, no. 1, pp. 117–121.Google Scholar
  19. 19.
    Perepelitsa, A.A., Mikhal’chuk, V.M., Savina, A.A., and Zhil’tsova, S.V., Vopr. Khim. Khim. Tekhnol., 2007, no. 2, pp. 149–159.Google Scholar
  20. 20.
    Volnyanskaya, R.I., Mikhal’chuk, V.M., and Nikolaevskii, A.N., Vopr. Khim. Khim. Tekhnol., 2004, no. 1, pp. 206–209.Google Scholar
  21. 21.
    Volnyanskaya, R.I., Maneshina, L.A., and Mikhal’chuk, V.M., Vopr. Khim. Khim. Tekhnol., 2005, no. 5, pp. 125–129.Google Scholar

Copyright information

© MAIK Nauka 2008

Authors and Affiliations

  • A. A. Lugovaya
    • 1
    • 2
  • V. M. Mikhal’chuk
    • 1
    • 2
  • V. A. Beloshenko
    • 1
    • 2
  • D. V. Gurtovoi
    • 1
    • 2
  1. 1.Donetsk National UniversityDonetskUkraine
  2. 2.Galkin Donetsk Physicotechnical InstituteNational Academy of Sciences of UkraineDonetskUkraine

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