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Russian Journal of Applied Chemistry

, Volume 79, Issue 6, pp 991–996 | Cite as

Copolymerization of acrylamide and sodium 2-acrylamido-2-methylpropanesulfonate in water-ethanol mixtures

  • V. F. Kurenkov
  • E. S. Shchelkonogova
  • A. V. Kurenkov
  • H. -G. Hartan
  • F. I. Lobanov
Macromolecular Chemistry and Polymeric Materials

Abstract

Homogeneous copolymerization of acrylamide and sodium 2-acrylamido-2-methylpropanesulfonate was carried out in water-ethanol mixtures at pH 9 in the presence of potassium peroxosulfate as promoter in the temperature range 40–70°C. The copolymerization kinetics and molecular characteristics of the copolymers formed were studied in relation to the composition of water-ethanol mixtures, reagent concentrations, temperature, and degree of monomer conversion.

Keywords

Copolymerization Intrinsic Viscosity Increase Water Content Water 3ethanol Mixture Copolymerization Rate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Lisovtsev, V.V., Rostokin, G.A., and Kulikova, A.N., in Khimicheskaya promyshlennost’: akrilaty i polivinilkhlorid (Chemical Industry: Acrylates and Polyvinyl Chloride), Moscow: NIIITEKHIM, 1984, pp. 1–20.Google Scholar
  2. 2.
    McCormick, C.L., Macromol. Sci. Chem., part A, 1985, vol. 22, nos. 5–7, pp. 955–982.Google Scholar
  3. 3.
    2-Acrylamido-2-Methylpropane Sulfonic Acid Monomer. Wickliffe, Ohio (USA): Lubrizol, 1994, pp. 1–18.Google Scholar
  4. 4.
    Kabanov, V.A., Zubov, V.P., and Semchikov, Yu.D., Kompleksno-radikal’naya polimerizatsiya (Complex-Radical Polymerization), Moscow: Khimiya, 1987.Google Scholar
  5. 5.
    Kurenkov, V.F., Antonovich, O.A., and Khusainova, A.F., Zh. Prikl. Khim., 2002, vol. 75, no. 10, pp. 1707–1711.Google Scholar
  6. 6.
    Kurenkov, V.F., Antonovich, O.A., Demina, T.A., and Selezneva, O.Yu., Vysokomol. Soedin., Ser. A, 2003, vol. 45, no. 8, pp. 1246–1252.Google Scholar
  7. 7.
    Kurenkov, V.F., Antonovich, O.A., Zigulyaeva, T.V., and Lobanov, F.I., Khim. Tekhnol., 2005, no. 7, pp. 14–19.Google Scholar
  8. 8.
    Kurenkov, V.F., Khairullin, M.R., and Utkeeva, A.R., Zh. Prikl. Khim., 1999, vol. 72, no. 7, pp. 1177–1182.Google Scholar
  9. 9.
    Charlot, G., Les Methods de la Chemie Analytique. Analyse Quantitative Minerale, Quatrieme Edition, Paris: Masson, 1961.Google Scholar
  10. 10.
    Kholodkova, L.V., Pavlyuchenko, V.N., Alekseeva, Z.M., and Andreeva, A.I., Kataliticheskie i initsiiruyushchie systemy dlya sinteza i modifikatsii polimerov (Catalytic and Initiating Systems for Synthesis and Modification of Polymers), Leningrad: Plastpolimer, 1984, pp. 90–104.Google Scholar
  11. 11.
    Kolthoff, I.M., and Miller, I.K., J. Am. Chem. Soc., 1951, vol. 73, no. 7, pp. 3055–3059.CrossRefGoogle Scholar
  12. 12.
    USSR Inventor’s Certificate, no. 235997.Google Scholar
  13. 13.
    Gromov, V.F., Bune, E.V., and Teleshov, E.N., Usp. Khim., 1994, vol. 63, no. 6, pp. 530–541.Google Scholar
  14. 14.
    Barabanova, A.I., Gromov, V.F., Bune, E.V., et al., Vysokomol. Soedin., Ser. A, 1994, vol. 36, no. 6, pp. 901–907.Google Scholar
  15. 15.
    Gromov, V.F., Bune, E.V., Barabanova, A.I., et al., Vysokomol. Soedin., Ser. A, 1995, vol. 37, no. 11, pp. 1818–1822.Google Scholar
  16. 16.
    Kurenkov, V.F., Zhelonkina, T.A., Meshcheryakov, A.N., and Lobanov, F.I., Zh. Prikl. Khim., 2005, vol. 78, no. 10, pp. 1697–1702.Google Scholar

Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • V. F. Kurenkov
    • 1
    • 2
    • 3
  • E. S. Shchelkonogova
    • 1
    • 2
    • 3
  • A. V. Kurenkov
    • 1
    • 2
    • 3
  • H. -G. Hartan
    • 1
    • 2
    • 3
  • F. I. Lobanov
    • 1
    • 2
    • 3
  1. 1.Kazan State Technological UniversityKazanRussia
  2. 2.StockhausenGmbH KrefeldGermany
  3. 3.Degussa Euraziya Limited Liability CompanyMoscowRussia

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