Skip to main content
SpringerLink
Log in

Heteroligand Complexes of Copper(II) with Malonic and Adipic Acids Dihydrazides and L-Histidine

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Using the methods of pH-metry and mathematical simulation, we studied the complex formation in the copper(II)–malonic (L)/adipic acid (L')–L-histidine (HisH) ternary systems in aqueous medium against 1.0 M KNO3 solution at 25.0°C. The stability constants of (1 : 1 : 1) heteroligand complexes were determined. Quantum chemical calculations of the structures of heteroligand complexes were performed. It was revealed that the Cu(His)(L)+ and Cu(His)(L')+ complexes exist predominantly in the cis-form.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Fridman, Ya.D., Svanidze, O.P., Dolgashova, N.V., and Gogorishvili, P.V., Izv. Akad. Nauk Kirgiz. SSR, 1973, no. 6, p. 54.

    Google Scholar 

  2. Fridman, Ya.D., Svanidze, O.P., Dolgashova, N.V., and Gogorishvili, P.V., Zh. Neorg. Khim., 1974, vol. 19, no. 12, p. 3304.

    CAS  Google Scholar 

  3. Karkarashvili, M.V. and Beshkenadze, I.A., Issl. v Obl. Khimii Kompl. i Prostykh Soed. Nekotorykh Perekh. i Redkikh Metallov, 1978, no. 3, p. 32.

    CAS  Google Scholar 

  4. Karkarashvili, M.V. and Beshkenadze, I.A., Issl. v Obl. Khimii Kompl. i Prostykh Soed. Nekotorykh Perekh. i Redkikh Metallov, 1978, no. 3, p. 44.

    CAS  Google Scholar 

  5. Troshanin, N.V., Razryvina, A.A., Gilyazetdinov, E.M., Bychkova, T.I., and Shtyrlin, V.G., Uchenye Zapiski Kazan. Univ., Ser. Estestv. Nauki, 2017, vol. 159, no. 1, p. 40.

    CAS  Google Scholar 

  6. Bychkova, T.I., Shtyrlin, V.G., and Zakharov, A.V., Zh. Neorg. Khim., 1989, vol. 34, no. 11, p. 2820.

    CAS  Google Scholar 

  7. Shtyrlin, V.G., Zyavkina, Yu.I., Gilyazetdinov, E.M., Bukharov, M.S., Krutikov, A.A., Garipov, R.R., Mukhtarov, A.S., and Zakharov, A.V., Dalton Trans., 2012, vol. 41, p. 1216. https://doi.org/10.1039/c1dt11309g

    Article  CAS  PubMed  Google Scholar 

  8. Afanas’eva, G.V., Bychkova, T.I., Shtyrlin, V.G., Shakirova, A.R., and Zakharov, A.V., Russ. J. Gen. Chem., 2006, vol. 76, no. 5, p. 757. https://doi.org/10.1134/S1070363206050185

    Article  CAS  Google Scholar 

  9. Bychkova, T.I., Afanas’eva, G.V., and Izhboldina, E.V., Uchenye Zap. Kazan. Univ., Ser. Estestv. Nauki, 2009, vol. 151, no. 4, p. 39.

    Google Scholar 

  10. Yatsimirskii, K.B., Kriss, E.E., and Gvyazdovskaya, V.L., Konstanty Ustoichivosti Kompleksov Metallov s Bioligandami: Spravochnik (Stability Constants of Complexes of Metals with Bioligands: Handbook), Kiev: Naukova Dumka, 1979.

  11. Sigel, H., IUPAC Coord. Chem. 20, Invit. Lect. 20 Int. Conf. Coord. Chem. Calcutta1979, Oxford: Pergamon Press, 1980, p. 27.

  12. Beck, M.T. and Nagypal, I., Chemistry of Complex Equilibria, Budapest: Akad. Kiado, 1989.

  13. Bukharov, M.S., Shtyrlin, V.G., Mukhtarov, A.Sh., Mamin, G.V., Stapf, S., Mattea, C., Krutikov, A.A., Il’in, A.N., and Serov, N.Yu., Phys. Chem. Chem. Phys., 2014, vol. 16, no. 20, p. 9411. https://doi.org/10.1039/c4cp00255e

    Article  CAS  PubMed  Google Scholar 

  14. Bukharov, M.S., Shtyrlin, V.G., Mamin, G.V., Stapf, S., Mattea, C., Mukhtarov, A.Sh., Serov, N.Yu., and Gilyazetdinov, E.M., Inorg. Chem., 2015, vol. 54, no. 20, p. 9777. https://doi.org/10.1021/acs.inorgchem.5b01467

    Article  CAS  PubMed  Google Scholar 

  15. Bukharov, M.S., Shtyrlin, V.G., Gilyazetdinov, E.M., Serov, N.Y., and Madzhidov, T.I., J. Comput. Chem., 2018, vol. 39, no. 14, p. 821. https://doi.org/10.1002/jcc.25154

    Article  CAS  PubMed  Google Scholar 

  16. Cossi, M., Rega, N., Scalmani, G., and Barone, V., J. Comput. Chem., 2003, vol. 24, no. 6, p. 669. https://doi.org/10.1002/jcc.10189

    Article  CAS  PubMed  Google Scholar 

  17. Smith, P.F.S., Organic Reactions, Adams, K., Ed., New York: John Wiley and Sons, 1948, vol. 3.

  18. Krutikov, A.A., Shtyrlin, V.G., Spiridonov, A.O., Serov, N.Yu., Il’yin, A.N., Bukharov, M.S., and Gilyazetdinov, E.M., J. Phys., 2012, vol. 394, p. 012031. https://doi.org/10.1088/1742-6596/394/1/012031

    Article  CAS  Google Scholar 

  19. Shtyrlin, V.G., Gilyazetdinov, E.M., Serov, N.Yu., Pyreu, D.F., Bukharov, M.S., Krutikov, A.A., Aksenin, N.S., Gizatullin, A.I., and Zakharov, A.V., Inorg. Chim. Acta, 2018, vol. 477, p. 135. https://doi.org/10.1016/j.ica.2018.02.018

    Article  CAS  Google Scholar 

  20. Kohn, W., Becke, A.D., and Parr, R.G., J. Phys. Chem., 1996, vol. 100, no. 31, p. 12974. https://doi.org/10.1021/jp960669l

    Article  CAS  Google Scholar 

  21. Schmidt, M.W., Baldridge, K.K., Boatz, J.A., Elbert, S.T., Gordon, M.S., Jensen, J.H., Koseki, S., Matsunaga, N., Nguyen, K.A., Su, S.J., Windus, T.L., Dupuis, M., and Montgomery, J.A., J. Comput. Chem., 1993, vol. 14, no. 11, p. 1347. https://doi.org/10.1002/jcc.540141112

    Article  CAS  Google Scholar 

  22. Becke, A.D., J. Chem. Phys., 1993, vol. 98, no. 7, p. 5648. https://doi.org/10.1063/1.464913

    Article  CAS  Google Scholar 

  23. Lee, C.T., Yang, W.T., and Parr, R.G., Phys. Rev. (B), 1988, vol. 37, no. 2, p. 785. https://doi.org/10.1103/PhysRevB.37.785

    Article  CAS  Google Scholar 

  24. Yanai, T., Tew, D.P., and Handy, N.C., Chem. Phys. Lett., 2004, vol. 393, p. 51. https://doi.org/10.1016/j.cplett.2004.06.011

    Article  CAS  Google Scholar 

  25. Schäfer, A., Huber, C., and Ahlrichs, R., J. Chem. Phys., 1994, vol. 100, no. 8, p. 5829. https://doi.org/10.1063/1.467146

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kazan (Volga Region) Federal University, 420008, Kazan, Russia

    N. V. Troshanin, E. M. Gilyazetdinov, T. I. Bychkova & V. G. Shtyrlin

Authors
  1. N. V. Troshanin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. M. Gilyazetdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. I. Bychkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Shtyrlin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Troshanin.

Ethics declarations

No conflict of interest was declared by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Troshanin, N.V., Gilyazetdinov, E.M., Bychkova, T.I. et al. Heteroligand Complexes of Copper(II) with Malonic and Adipic Acids Dihydrazides and L-Histidine. Russ J Gen Chem 90, 404–409 (2020). https://doi.org/10.1134/S1070363220030123

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363220030123

Keywords:

Search

Navigation