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Russian Journal of General Chemistry

, Volume 89, Issue 10, pp 2154–2158 | Cite as

Alkoxytelluration of Styrene with Tellurium Tetrahalides

  • V. A. PotapovEmail author
  • A. G. Khabibulina
  • S. I. Udalova
  • M. V. Musalov
  • M. V. Musalova
  • I. V. Shkurchenko
  • A. I. Albanov
  • S. V. Amosova
Letters to the Editor
  • 6 Downloads

Abstract

An efficient synthesis of the earlier unknown trichloro- and tribromo(2-ahkoxy-2-phenylethyl)-λ4-tellanes with yields of 90 to 100% has been developed basing on alkoxytelluration of styrene with tellurium tetrachloride or tetrabromide in the presence of alcohols. The reduction of tellanes in the NaBH4-H2O-THF and Na2S2O5-H2O-C6H6 systems has afforded bis(2-alkoxy-2-phenylethyl)ditellanes in up to 95% yield.

Keywords

alkoxytelluration styrene tellurium tetrabromide tellurium tetrachloride tellanes ditellanes 

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Notes

Funding

This study was financially supported by the Russian Foundation for Basic Research (project 18-03-01007_a). Spectral studies were performed using the equipment of the Baikal Analytical Center for Collective Usage of Siberian Branch of Russian Academy of Sciences.

Conflict of Interest

No conflict of interest was declared by the authors.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. A. Potapov
    • 1
    Email author
  • A. G. Khabibulina
    • 1
  • S. I. Udalova
    • 1
  • M. V. Musalov
    • 1
  • M. V. Musalova
    • 1
  • I. V. Shkurchenko
    • 2
  • A. I. Albanov
    • 1
  • S. V. Amosova
    • 1
  1. 1.A.E. Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia
  2. 2.Irkutsk State UniversityIrkutskRussia

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