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Russian Journal of General Chemistry

, Volume 89, Issue 7, pp 1477–1484 | Cite as

Dispersion Oxidative Polymerization of Pyrrole in Aqueous Solutions of Polyvinyl Alcohol

  • Ya. O. MezhuevEmail author
  • I. V. Plyushchii
  • Yu. V. Korshak
  • M. I. Shtil’man
  • I. A. Gritskova
Article
  • 2 Downloads

Abstract

Kinetics of the oxidative polymerization of pyrrole in an aqueous solution of poly(vinyl alcohol) under the action of ammonium peroxydisulfate has been studied. The obtained kinetic data has been quantitatively described with regard to the formation of a new phase, the values of activation energy for the non-catalytic and catalytic stages of the oxidative pyrrole polymerization have been determined. Various mechanisms of oxidative polymerization of pyrrole have been critically evaluated, and the calculated kinetic parameters have been compared with their values available in the literature for oxidative pyrrole polymerization in the absence of stabilizers.

Keywords

polypyrrole oxidative polymerization pyrrole poly(vinyl alcohol) kinetics 

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Notes

Funding

This study was financially supported by D.I. Mendeleev University of Chemical Technology (project no. 006-2018).

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Ya. O. Mezhuev
    • 1
    Email author
  • I. V. Plyushchii
    • 1
  • Yu. V. Korshak
    • 1
  • M. I. Shtil’man
    • 1
  • I. A. Gritskova
    • 2
  1. 1.D.I. Mendeleev University of Chemical TechnologyMoscowRussia
  2. 2.M.V. Lomonosov Institute of Fine Chemical TechnologiesRussian University of TechnologyMoscowRussia

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