Russian Journal of General Chemistry

, Volume 89, Issue 7, pp 1447–1450 | Cite as

Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles

  • V. D. MakhaevEmail author
  • L. A. Petrova
  • Yu. M. Shulga


Solid-phase reaction of copper(I) chloride with sodium β-diketonates under mechanical activation in a vibration ball mill involves disproportionation of CuCl with the formation of the corresponding copper(II) β-diketonate and highly reactive X-ray amorphous metallic copper nanoparticles. The effect of reaction conditions on the process and some properties of the activated mixtures have been studied.


mechanical activation solid-phase synthesis copper(II) β-diketonates nanomaterials nanosized copper 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.



This study was financially supported by the Ministry of Education and Science within the framework of State contract (State registration no. 01201361869)..


  1. 1.
    Cave, G.W.V., Raston, C.L., and Scott, J.L., Chem. Commun., 2001, no. 21, p. 2159. doi
  2. 2.
    Avvakumov, E.G., Mekhanicheskie metody aktivatsii khimicheskikh protsessov, (Mechanical Methods of Activation of Chemical Processes), Novosibirsk: Nauka 1986.Google Scholar
  3. 3.
    Boldyrev, V.V, Russ. Chem. Rev., 2006, vol. 75, no. 3, p. 177. doi CrossRefGoogle Scholar
  4. 4.
    Beyer, M.K. and Clausen-Schaumann, H., Chem. Rev., 2005, vol. 105, no. 8, p. 2921. doi CrossRefGoogle Scholar
  5. 5.
    Rightmire, N.R. and Hanusa, T.P., Dalton Trans., 2016, vol. 45, no. 6, p. 2352. doi CrossRefGoogle Scholar
  6. 6.
    Borisov, A.P., Petrova L.A., Karpova, T.P., and Makhaev, V.D., Russ. J. Inorg. Chem., 1996, vol. 41, no. 3, p. 394.Google Scholar
  7. 7.
    Petrova, L.A., Borisov, A.P., Aleshin, V.V., and Makhaev, V.D., Russ. J. Inorg. Chem., 2001, vol. 46, no. 10, p. 1501.Google Scholar
  8. 8.
    Makhaev, V.D. and Petrova, L.A., Russ. J. Gen. Chem., 2017, vol. 87, no. 6, p. 1105. doi CrossRefGoogle Scholar
  9. 9.
    Nakamoto, K., McCarthy, P.J., and Martell, A.E., J. Am. Chem. Soc., 1961, vol. 83, no. 6, p. 1272. doi CrossRefGoogle Scholar
  10. 10.
    Mikami, M., Nakawaga, I., and Shimanouchi, T., Spectrochim. Acta, Part A, 1967, vol. 23, no. 4, p. 1037. doi CrossRefGoogle Scholar
  11. 11.
    Moshier, R.W. and Sievers, R.E., Gas Chromatography of Metal Chelates, Oxford: Pergamon, 1965.Google Scholar
  12. 12.
    Gusev, A.I., Nanomaterialy, nanostruktury, nanotekhnologii, (Nanomaterials, Nanostructures, and Nanotechnologies), Moscow: Fizmatlit 2005, p. 169.Google Scholar
  13. 13.
    Morris, M.L., Moshier, R.W., and Sievers, R.E., Inorg. Chem., 1963, vol. 2, no. 2, p. 411. doi CrossRefGoogle Scholar
  14. 14.
    Shyamal Mondat and Bhattacharyya, S.R., RSC Adv., 2015, vol. 5, no. 120, p. 99425. doi CrossRefGoogle Scholar
  15. 15.
    Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Khimiya, 1964, vol. 2, p. 123.Google Scholar
  16. 16.
    Suryanarayanan, R., Frey, C.A., Sastry, S.M.L., Waller, B.E., Bates, S.E., and Buhro, W.E., J. Mater. Res., 1996, vol. 11, no. 2, p. 439. doi CrossRefGoogle Scholar
  17. 17.
    Gawande, M.B., Goswami, A., Felpin, F.-X., Asefa, T., Huang, X., Silva, R., Zou, X., Zboril, R., and Varma, R.S., Chem. Rev., 2016, vol. 116, no. 6, p. 3722. doi CrossRefGoogle Scholar
  18. 18.
    Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva, (Pure Chemicals), Moscow: Khimiya 1974, p. 240.Google Scholar
  19. 19.
    Bertrand, J.A. and Kaplan, R.J., Inorg. Chem., 1966, vol. 5, no. 3, p. 489. doi CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. D. Makhaev
    • 1
    Email author
  • L. A. Petrova
    • 1
  • Yu. M. Shulga
    • 1
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

Personalised recommendations