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Russian Journal of General Chemistry

, Volume 89, Issue 2, pp 277–280 | Cite as

Synthesis and Structure of Platinum Diethyl Sulfoxide Complexes

  • A. R. TkachevaEmail author
  • V. V. Sharutin
  • O. K. Sharutina
Article
  • 5 Downloads

Abstract

The reaction of tetraorganylphosphonium and tetraethylammonium chlorides with hexachloroplatinic acid hydrate in a mixture of acetonitrile and diethyl sulfoxide produced [Ph3PEt][PtCl5(deso-S)] and [Et4N][PtCl5(deso-S)] complexes containing tetrahedral tetraorganylphosphonium or tetraethylammonium cations and octahedral diethylsulfoxidopentachloroplatinate anions.

Keywords

triphenylethylphosphonium chloride tetraethylammonium chloride hexachloroplatinic acid diethyl sulfoxide diethylsulfoxidopentachloroplatinate anion 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. R. Tkacheva
    • 1
    Email author
  • V. V. Sharutin
    • 1
  • O. K. Sharutina
    • 1
  1. 1.National Research South Ural State UniversityChelyabinskRussia

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