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Russian Journal of General Chemistry

, Volume 89, Issue 1, pp 76–81 | Cite as

Synthesis and Structure of μ2-Oxobis(carboxylatotriarylantimony)

  • V. V. SharutinEmail author
  • O. K. Sharutina
  • A. N. Efremov
  • E. V. Artem’eva
Article
  • 3 Downloads

Abstract

Binuclear antimony compounds with a bridging oxygen atom [Ph3SbOC(O)R]2O (R = CF2CF3, CF2CF2CF3), [(4-МеC6H4)3SbOC(O)CF2CF3]2O, [(3-FC6H4)3SbOC(O)R]2O (R = C6F5, CF2CF3) have been synthesized by reacting equimolar amounts of triarylantimony, carboxylic acid and tert-butyl hydroperoxide in diethyl ether. According to X-ray diffraction data, in the molecules of compounds obtained, the Sb atoms have a trigonal bipyramid coordination with carboxylate ligands and a bridging oxygen atom in axial positions. The intramolecular distances Sb···O with a carbonyl oxygen atom are less than the sum of the van der Waals radii of Sb and O by ~0.2–0.4 Å.

Keywords

μ2-oxobis(carboxylatotriarylantimony) oxidative synthesis binuclear triarylantimony carboxylates 

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References

  1. 1.
    Ferguson, G., Kaither, B., Glidewell, С., Ferguson, G., Kaither, B., Glidewell, C., and Smith, S.J., J. Organomet. Chem., 1991, vol. 419, p. 283. doi  https://doi.org/10.1016/0022-328X(91)80241-B CrossRefGoogle Scholar
  2. 2.
    Qin, W., Yasuike, S., Kakusawa, N., Qin, W., Yasuike, S., Kakusawa, N., Sugawara, Y., Kawahata, M., Yamaguchi, K., and Kurita, J., J. Organomet. Chem., 2008, vol. 693, p. 109. doi  https://doi.org/10.1016/j.jorganchem.2007.10.030 CrossRefGoogle Scholar
  3. 3.
    Sharutin, V.V. and Sharutina, O.K., Russ. Chem. Bull., 2017, vol. 66, p. 707. doi  https://doi.org/10.1007/s11172-017-1796-6 CrossRefGoogle Scholar
  4. 4.
    Sharutin, V.V., Sharutina, O.K., Reshetnikova, R.V., Lobanova, E.V., and Efremov, A.N., Russ. J. Inorg. Chem., 2017, vol. 62, p. 1450. doi  https://doi.org/10.1134/S003602361711016X CrossRefGoogle Scholar
  5. 5.
    Sharutin, V.V., Sharutina, O.K., and Efremov, A.N., Russ. J. Inorg. Chem., 2016, vol. 61, p. 43. doi  https://doi.org/10.1134/S003602361601023X CrossRefGoogle Scholar
  6. 6.
    Yu, L., Ma, Y-Q., Wang, G-C., and Li, J-S., Heteroatom. Chem., 2004, vol. 15, p. 32. doi  https://doi.org/10.1002/hc.10208 CrossRefGoogle Scholar
  7. 7.
    Yu, L., Ma, Y-Q., Liu, R-C., Yu, L., Ma, Y.Q., Liu, R.C., Wang, G.C., Li, J.S., Du, G.H., and Hu, J.J., Polyhedron, 2004, vol. 23, p. 823. doi  https://doi.org/10.1016/j.poly.2003.12.002 CrossRefGoogle Scholar
  8. 8.
    Hadjikakou, S.K., Ozturk, I.I., Banti, C.N., and Kourkoumelis, N., Hadjiliadis, N.J., Inorg. Biochem., 2015, vol. 153, p. 293. doi  https://doi.org/10.1016/j.jinorgbio.2015.06.006 CrossRefGoogle Scholar
  9. 9.
    Ali, M.I., Rauf, M.K., Badshah, A., Ali, M.I., Rauf, M.K., Badshah, A., Kumar, I., Forsyth, C.M., Junk, P.C., Kedzierski, L., and Andrews, P.C., Dalton Trans., 2013, vol. 42, p. 16733. doi  https://doi.org/10.1039/C3DT51382C CrossRefGoogle Scholar
  10. 10.
    Sharutin, V.V., Sharutina, O.K., and Senchurin, V.S., Russ. J. Coord. Chem., 2014, vol. 40, p. 109. doi  https://doi.org/10.1134/S1070328414020109 CrossRefGoogle Scholar
  11. 11.
    Quan, L., Yin, H., and Wang, D., Acta Crystallogr. (E), 2008, vol. 64, p. m349. doi  https://doi.org/10.1107/S1600536808000676
  12. 12.
    Quan, L., Yin, H., and Wang, D., Acta Crystallogr. (E), 2009, vol. 65, p. m99. doi  https://doi.org/10.1107/S1600536808042335
  13. 13.
    Gibbons, M.N. and Sowerby, D.B., J. Organomet. Chem., 1998, vol. 555, p. 271. doi  https://doi.org/10.1016/S0022-328X(97)00759-6.CrossRefGoogle Scholar
  14. 14.
    Sharutin, V.V., Pakusina, A.P., Nasonova, N.V., Sharutina, O.K., Gerasimenko, A.V., ansd Pushilin, M.A., Khimiya i Komp’yuternoe Modelirovanie. Butrlovsk. Soobshch. (Chemistry and Computer Simulation. Butlerov Reports), 2002, no. 11, p. 13.Google Scholar
  15. 15.
    Bruker (1998). SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System. Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
  16. 16.
    Bruker (1998). SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data. Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
  17. 17.
    Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H.J., J. Appl. Cryst., 2009, vol. 42, p. 339. doi  https://doi.org/10.1107/S0021889808042726 CrossRefGoogle Scholar
  18. 18.
    Sharutin, V.V. and Senchurin, V.S., Imennye reaktsii v khimii elementorganicheskikh soedinenii (Nominal Reaction in Chemistry of Organoelemental Compounds), Celyabinsk: Izd. Tsentr YuUrGU, 2011.Google Scholar
  19. 19.
    Glidewell, C., J. Orgnomet. Chem., 1988, vol. 356, p. 151. doi  https://doi.org/10.1016/0022-328X(88)83084-5 CrossRefGoogle Scholar
  20. 20.
    Tiekink, E.R.T., J. Organomet. Chem., 1987, vol. 333, p. 199. doi  https://doi.org/10.1016/0022-328X(87)85152-5 CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. V. Sharutin
    • 1
    Email author
  • O. K. Sharutina
    • 1
  • A. N. Efremov
    • 1
  • E. V. Artem’eva
    • 1
  1. 1.National Research South Ural State UniversityChelyabinskRussia

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