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Russian Journal of General Chemistry

, Volume 89, Issue 1, pp 51–58 | Cite as

Reaction of 3a,6a-Diaza-1,4-diphosphapentalene with Substituted Acetylenes

  • A. N. KornevEmail author
  • V. E. Galperin
  • Yu. S. Panova
  • V. V. Sushev
  • G. K. Fukin
  • E. V. Baranov
  • G. A. Abakumov
Article
  • 5 Downloads

Abstract

The reaction of 3a,6a-diaza-1,4-diphosphapentalene with 1-bromo-2-phenylacetylene has led to the formation of 1,1-bis(phenylethynyl)- and 1,4-dibromo-3a,6a-diaza-1,4-diphosphapentalene. The first has been also prepared via a different route by the reaction of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalene with lithium phenylacetylenide in 96% yield. No isomeric 1,4-bis(phenylethynyl)-DDP has been formed in this reaction. The reaction in the 3a,6a-diaza-1,4-diphosphapentalene–[Ph3PC≡CPh]Br–carbazole three-component system proceeds as addition of carbazole to the initially formed complex of 3a,6a-diaza-1,4-diphosphapentalene with [Ph3PC≡CPh]Br with the rupture of the P–N bond. The products and intermediates of the reaction have been simulated by B3LYP/6-31+G(d) method.

Keywords

heterophospholes heteropentalenes phosphorus ylides carbenoids 

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. N. Kornev
    • 1
    Email author
  • V. E. Galperin
    • 1
  • Yu. S. Panova
    • 1
  • V. V. Sushev
    • 1
  • G. K. Fukin
    • 1
  • E. V. Baranov
    • 1
  • G. A. Abakumov
    • 1
  1. 1.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhny NovgorodRussia

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