Russian Journal of General Chemistry

, Volume 88, Issue 13, pp 2976–2981 | Cite as

Behavior of Sulfide Ore Elements in the Oxidation of Concentration Tailings under Cryogenic Conditions (Dalnegorsk District, Far East)

  • V. P. ZverevaEmail author
  • A. D. Pyatakov


Oxidation processes in the sulfide component of the concentration located in the Dalnegorsk district were modeled in the range from–25 to 0°C. The modeling showed crystallization of the following minerals from the model solutions: hypergene Fe, Cu, Pb, Zn, Al, Mg, and Ca sulfate, arsenate, silicate, oxide, and hydroxide minerals at the tailing dumps of the Central concentrating mill and hypergene Fe, Pb, Sb, and Ca sulfate, carbonate, oxide, and hydroxide minerals at the tailing dumps of the Krasnorechensk concentrating mill. The concentrations of sulfide ore elements in the solution in the negative temperature range are much higher compared to those at positive temperatures. This takes place, because the most part of the solution passes to the solid phase (ice), and the volume of the liquid phase decreases. As a result, the hydrosphere of the district is experiencing severe anthropogenic impact from the elements of sulfide ores (S, Zn, Cu, Pb, Fe, Ag, As, and Sb) and their host rocks (Mg, K, Na, Ca, Si and Al).


physicochemical modeling hypergenesis tailings tailing dump environmental assessment verification 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Zvereva, V.P., Yastremskaya, E.A., and Lysenko, A.I., Russ. J. Gen. Chem., 2014, vol. 84, no. 13, p. 2643. doi CrossRefGoogle Scholar
  2. 2.
    Zvereva, V.P., Lysenko, A.I., and Kostina, A.M., Adv. Mater. Res., 2014, vols. 989–994, p. 1301. doi Google Scholar
  3. 3.
    Zvereva, V.P., Pyatakov, A.D., Lysenko, A.I., and Kostina, A.M., WIT Trans. Built Environ., 2014, vol. 88, p. 493. doi Google Scholar
  4. 4.
    Zvereva, V.P., Kostina, A.M., and Lysenko, A.I., Future Communication Technology and Engineering, Chan, K., Ed., Boca Raton: CRC, 2015, p. 287. doi CrossRefGoogle Scholar
  5. 5.
    Zvereva, V.P., Pyatakov, A.D., Kostina, A.M., Lysenko, A.I., Frolov, K.R., Russ. J. Gen. Chem., 2015, vol. 85, no. 13, p. 2956. doi CrossRefGoogle Scholar
  6. 6.
    Zvereva, V.P., Lysenko, A.I., and Kostina, A.M., Russ. J. Gen. Chem., 2016, vol. 86, no. 13, p. 2997. doi CrossRefGoogle Scholar
  7. 7.
    Vitvitskii, G.N., Dal’nii Vostok. Fiziko-geograficheskaya kharakteristika (Far East. Physical Geogpraphic Characteristic), Moscow: Akad. Nauk SSSR, 1961, p. 93.Google Scholar
  8. 8.
    Karpov, I.K., Fiziko-khimicheskoe modelirovanie na EVM v geokhimii (Computer Simulation of Physico-Chemical Processes in Geochemistry), Nauka: Novosibirsk, 1981.Google Scholar
  9. 9.
    Horne, R.A., Marine Chemistry. The Structure of Water and the Chemistry of the Hydrosphere, New York: Wiley, 1969.Google Scholar
  10. 10.
    Bulavko, N.V., Mineralogiya skarnovykh mestorozhdenii Dal’negorskogo rudnogo polya (Primor’e) [Mineralogy of Skarn Deposits of the Dalnegorsk ore field (Primorye), Vladivostok: Dal’nevostochnoe Knizhnoe Izdatel’stvo, 2000.Google Scholar
  11. 11.
    Tarasenko, I.A. and Zin’kov, A.V., Ekologicheskie posledstviya mineralogo-geokhimicheskikh preobrazovanii khvostov obogashcheniya Sn-Ag-Pb-Zn rud (Ecological Consequences of Mineralogical and Geochemical Transformations of Sn-Ag-Pb-Zn Ore Tailings), Vladivostok: Dal’nauka, 2001.Google Scholar
  12. 12.
    Vasilenko, G.P., Cand. Sci. (Geol.-Mineral.) Dissertation, Vladivostok, 1976.Google Scholar
  13. 13.
    Burago, A.I. and Shlykov, S.A., Komplekt geokhimicheskikh kart yuzhnoy poloviny Primorskogo kraya. Masshtab 1:1000000 i ob”yasnitel’naya zapiska k nim. Prom. otchet TOO MIF “Ekotsentr” po ob”ektu uchastok Primorskiy za 1994–1997 g. (A Set of Geochemical Mmaps of the Southern Half of Primorsky Krai. Scale 1: 1.000.000 and Explanatory Note to Them. Interim Report on the Primorsky Region Object 1994–1997), Vladivostok, 1997.Google Scholar

Copyright information

© Pleiades Publishing, Ltd 2019

Authors and Affiliations

  1. 1.Far Eastern Federal UniversityVladivostokRussia
  2. 2.Far East Geological Institute, Far East BranchRussian Academy of SciencesVladivostokRussia

Personalised recommendations