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Russian Journal of General Chemistry

, Volume 88, Issue 11, pp 2347–2353 | Cite as

Synthesis of Mixed-Ligand Nitrileand Carbonyl–Isocyanide Complexes of Platinum(II) and Their Reaction with P-Toluenesulfonyl Hydrazide

  • R. A. Popov
  • A. S. Novikov
  • A. S. Mikherdov
Article
  • 5 Downloads

Abstract

Mixed-ligand nitrile- and carbonyl-isocyanide complexes of platinum(II) trans-[PtCl2(NCEt)CNXyl] and trans-[PtCl2(CO)CNXyl] (Xyl = 2,6-Me2C6H3) have been prepared for the first time. The compounds have been characterized by mass spectrometry, IR and NMR spectroscopy. Reactivity of the prepared complexes towards N-nucleophiles has been studied using the reaction with p-toluenesulfonyl hydrazide as the example.

Keywords

platinum complexes isocyanide complexes nitrile complexes carbonyl complexes Hirshfeld surface analysis 

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References

  1. 1.
    Boyarskiy, V.P., Bokach, N.A., Luzyanin, K.V., and Kukushkin, V.Y., Chem. Rev., 2015, vol. 115, p. 2698. doi 10.1021/cr500380dCrossRefGoogle Scholar
  2. 2.
    Kinzhalov, M.A. and Boyarskii, V.P., Russ. J. Gen. Chem., 2015, vol. 85, no. 10, p. 2313. doi 10.1134/S1070363215100175CrossRefGoogle Scholar
  3. 3.
    Mikherdov, A.S., Novikov, A.S., Kinzhalov, M.A., Boyarskiy, V.P., Starova, G.L., Ivanov, A.Y., and Kukushkin, V.Y., Inorg. Chem., 2018, vol. 57, no. 6, p. 3420 doi 10.1021/acs.inorgchem.8b00190CrossRefGoogle Scholar
  4. 4.
    Kinzhalov, M.A., Timofeeva, S.A., Luzyanin, K.V., Boyarskiy, V.P., Yakimanskiy, A.A., Haukka, M., and Kukushkin, V.Yu., Organometallics, 2016, vol. 35, no. 2, p. 218. doi 10.1021/acs.organomet.5b00936CrossRefGoogle Scholar
  5. 5.
    Mikhaylov, V.N., Sorokoumov, V.N., Korvinson, K.A., Novikov, A.S., and Balova, I.A., Organometallics, 2016, vol. 35, no. 11, p. 1684. doi 10.1021/acs.organomet.6b00144CrossRefGoogle Scholar
  6. 6.
    Tšupova, S., Rudolph, M., Rominger, F., and Hashmi, A.S.K., Adv. Synth. Catal., 2016, vol. 358, no.24. 3999. doi 10.1002/adsc.201600615CrossRefGoogle Scholar
  7. 7.
    Anisimova, T.B., Kinzhalov, M.A., Guedes da Silva, M.F.C., Novikov, A.S., Kukushkin, V.Yu., Pombeiro, A.J.L., and Luzyanin, K.V., New J. Chem., 2017, vol. 41, p. 3246. doi 10.1039/C7NJ00529FCrossRefGoogle Scholar
  8. 8.
    Na, H. and Teets, T.S., J. Am. Chem. Soc., 2018, vol. 140, no. 20, p. 6353. doi 10.1021/jacs.8b02416CrossRefGoogle Scholar
  9. 9.
    Hubbert, C., Breunig, M., Carroll, K.J., Rominger, F., and Hashmi, A.S.K., Aust. J. Chem., 2014, vol. 67, no. 3, p. 469. doi 10.1071/CH13546CrossRefGoogle Scholar
  10. 10.
    Wurm, T., Hornung, J., O’Neill, M., Rudolph, M., Rominger, F., and Hashmi, A.S.K., Chem. Eur. J., 2017, vol. 23, no. 21, p. 5143. doi 10.1002/chem.201700214CrossRefGoogle Scholar
  11. 11.
    Mikherdov, A.S., Kinzhalov, M.A., Novikov, A.S., Boyarskiy, V.P., Boyarskaya, I.A., Dar’in, D.V., Starova, G.L., and Kukushkin, V.Y., J. Am. Chem. Soc., 2016, vol. 138, no. 42, p. 14129. doi 10.1021/jacs.6b09133CrossRefGoogle Scholar
  12. 12.
    Mikherdov, A.S., Kinzhalov, M.A., Novikov, A.S., Boyarskiy, V.P., Boyarskaya, I.A., Avdontceva, M.S., and Kukushkin, V.Y., Inorg. Chem., 2018, vol. 57, no. 11, p. 6722. doi 10.1021/acs.inorgchem.8b01027CrossRefGoogle Scholar
  13. 13.
    Mikherdov, A.S., Novikov, A.S., Kinzhalov, M.A., Zolotarev, A.A., and Boyarskiy, V.P., Crystals, 2018, vol. 8, no. 3, p. 112. doi 10.3390/cryst8030112CrossRefGoogle Scholar
  14. 14.
    Mikherdov, A.S., Tiuftiakov, N.Yu., Polukeev, V.A., and Boyarskii, V.P., Russ. J. Gen. Chem., 2018, vol. 88, no. 4, p. 713. doi 10.1134/S1070363218040151CrossRefGoogle Scholar
  15. 15.
    Boyarskiy, V.P., Luzyanin, K.V., and Kukushkin, V.Y., Coord. Chem. Rev., 2012, vol. 256, nos. 17–18, p. 2029. doi 10.1016/j.ccr.2012.04.022CrossRefGoogle Scholar
  16. 16.
    Slaughter, L.M., ACS Catal., 2012, vol. 2, no. 8, p. 1802. doi 10.1021/cs300300yCrossRefGoogle Scholar
  17. 17.
    Kinzhalov, M.A., Luzyanin, K.V., Boyarskiy, V.P., Haukka, M., and Kukushkin, V.Y., Organometallics, 2013, vol. 32, p. 5212. doi 10.1021/om4007592CrossRefGoogle Scholar
  18. 18.
    Savicheva, E.A., Kurandina, D.V., Nikiforov, V.A., and Boyarskiy, V.P., Tetrahedron Lett., 2014, vol. 55, p. 2101. doi 10.1016/j.tetlet.2014.02.044CrossRefGoogle Scholar
  19. 19.
    Ryabukhin, D.S., Sorokoumov, V.N., Savicheva, E.A., Boyarskiy, V.P., Balova, I.A., and Vasilyev, A.V., Tetrahedron Lett., 2013, vol. 54, p. 2369. doi 10.1016/j.tetlet.2013.02.086CrossRefGoogle Scholar
  20. 20.
    Miltsov, S.A., Karavan, V.S., Boyarsky, V.P., Gómezde Pedro, S., Alonso-Chamarro, J., and Puyol, M., Tetrahedron Lett., 2013, vol. 54, p. 1202. doi 10.1016/j.tetlet.2012.12.060CrossRefGoogle Scholar
  21. 21.
    Valishina, E.A., Guedes da Silva, M.F.C., Kinzhalov, M.A., Timofeeva, S.A., Buslaeva, T.M., Haukka, M., Pombeiro, A.J.L., Boyarskiy, V.P., Kukushkin, V.Y., and Luzyanin, K.V., J. Mol. Catal. (A), 2014, vol. 395, p. 162. doi 10.1016/j.molcata.2014.08.018CrossRefGoogle Scholar
  22. 22.
    Timofeeva, S.A., Kinzhalov, M.A., Valishina, E.A., Luzyanin, K.V., Boyarskiy, V.P., Buslaeva, T.M., Haukka, M., and Kukushkin, V.Y., J. Catal., 2015, vol. 329, p. 449. doi 10.1016/j.jcat.2015.06.001CrossRefGoogle Scholar
  23. 23.
    Boyarskaya, D.V. and Boyarskii, V.P., Russ. J. Gen. Chem., 2016, vol. 86, no. 9, p. 2033. doi 10.1134/S1070363216090085CrossRefGoogle Scholar
  24. 24.
    Boyarskii, V.P., Russ. J. Gen. Chem., 2017, vol. 87, no. 8, p. 1663. doi 10.1134/S1070363217080035CrossRefGoogle Scholar
  25. 25.
    Kinzhalov, M.A., Buldakov, A.V., Petrov, A.V., Mahmudov, K.T., Ivanov, A.Yu., and Suslonov, V.V., Russ. J. Gen. Chem., 2017, vol. 87, no. 11, p. 2605. doi 10.1134/S1070363217110159CrossRefGoogle Scholar
  26. 26.
    Kinzhalov, M.A., Kashina, M.V., Mikherdov, A.S., Katkova, S.A., and Suslonov, V.V., Russ. J. Gen. Chem., 2018, vol. 88, no. 6, p. 1180. doi 10.1134/S107036321806021XCrossRefGoogle Scholar
  27. 27.
    Crociani, B., Boschi, T., and Belluco, U., Inorg. Chem., 1970, vol. 9, no. 9, p. 2021. doi 10.1021/ic50091a013CrossRefGoogle Scholar
  28. 28.
    Crociani, B., Boschi, T., Nicolini, M., and Belluco, U., Inorg. Chem., 1971, vol. 11, no. 6, p. 1292. doi 10.1021/ic50112a028CrossRefGoogle Scholar
  29. 29.
    Calligaro, L., Uguagliati, P., Crociani, B., and Belluco, U., J. Organomet. Chem., 1975, vol. 92, no. 3, p.399.CrossRefGoogle Scholar
  30. 30.
    Han, Y. and Huynh, H.V., Dalton Trans., 2009, no. 12, p. 2201. doi 10.1039/B816471ACrossRefGoogle Scholar
  31. 31.
    Kinzhalov, M.A., Zolotarev, A.A., and Boyarskiy, V.P., J. Struct. Chem., 2016, vol. 57, no. 2, p. 822. doi 10.1134/S0022476616040302CrossRefGoogle Scholar
  32. 32.
    Kinzhalov, M.A., Luzyanin, K.V., Boyarskaya, I.A., Starova, G.L., and Boyarskiy, V.P., J. Mol. Struct., 2014, vol. 1068, no, p. 222. doi 10.1016/j.molstruc.2014.04.025CrossRefGoogle Scholar
  33. 33.
    Sluch, I.M., Miranda, A.J., Elbjeirami, O., Omary Md.A., and Slaughter, L.M., Inorg. Chem., 2012, vol. 51, no. 20, p. 10728. doi 10.1021/ic301104aCrossRefGoogle Scholar
  34. 34.
    Tskhovrebov, A.G., Luzyanin, K.V., Haukka, M., and Kukushkin, V.Y., J. Chem. Cryst., 2012, vol. 42, no. 12, p. 1170. doi 10.1007/s10870-012-0371-0CrossRefGoogle Scholar
  35. 35.
    Svensson, P., Lovqvist, K., Kukushkin, V.Yu., and Oskarsson, A., Acta Chem. Scand., 1995, vol. 49, p. 72. doi 10.3891/acta.chem.scand.49-0072CrossRefGoogle Scholar
  36. 36.
    Bondi, A., J. Phys. Chem., 1966, vol. 70, no. 9, p. 3006. doi 10.1021/j100881a503CrossRefGoogle Scholar
  37. 37.
    Sheldrick, G.M., Acta Crystalogr. (A), 2008, vol. 64, no, p. 112. doi 10.1107/S0108767307043930CrossRefGoogle Scholar
  38. 38.
    Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Cryst., 2009, vol. 42, p. 339. doi 10.1107/S0021889808042726CrossRefGoogle Scholar
  39. 39.
    CrysAlisPro, A.T., Version 1.171.36.20 (release 27-06-2012).Google Scholar
  40. 40.
    McKinnon, J.J., Jayatilaka, D., and Spackman, M.A., Chem. Commun., 2007, no. 37, p. 3814. doi 10.1039/B704980CCrossRefGoogle Scholar
  41. 41.
    Wolff, S.K., Grimwood, D.J., McKinnon, J.J., Turner, M.J., Jayatilaka, D., and Spackman, M.A., Crystal Explorer, Version 3.1, University of Western Australia, 2012.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • R. A. Popov
    • 1
  • A. S. Novikov
    • 1
  • A. S. Mikherdov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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