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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2119–2124 | Cite as

Formation of Homo- and Heteronuclear Platinum(II) and Palladium(II) Carbene Complexes in the Reactions of Coordinated Isocyanides with Aminothiazaheterocycles

  • A. S. Mikherdov
  • Yu. A. Orekhova
  • V. P. BoyarskiiEmail author
Article
  • 9 Downloads

Abstract

The reaction of 5-(trifluoromethyl)-1,3,4-thiadiazol-2-amine with cis-dichlorobis(2,6-dimethylphenyl isocyanide)platinum(II) (cis-[PtCl2(CNXyl)2], Xyl = 2,6-Me2C6H3) gave platinum(II) monocarbene complex whose deprotonation with an organic base generated a nucleophilic species capable of reacting with palladium(II) and platinum(II) bis(isocyanide) complexes to afford homo- and heteronuclear isocyanide/carbene structures.

Keywords

platinum(II) diaminocarbene complexes palladium(II) diaminocarbene complexes heteronuclear carbene complexes isocyanide ligands aminothiazaheterocycles 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. S. Mikherdov
    • 1
  • Yu. A. Orekhova
    • 1
  • V. P. Boyarskii
    • 1
    Email author
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia

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